首页|改性2-甲基戊二胺固化剂的制备及其性能研究

改性2-甲基戊二胺固化剂的制备及其性能研究

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为了改进环氧树脂固化速度以及固化后的物理性能,用环氧树脂NPEL-128(EP128)对固化剂2-甲基戊二胺(DYTEK-A)改性,并加入苯甲醇(BA)稀释,通过改变用量得到不同改性固化剂.改性固化剂与环氧树脂混合固化后的材料最大硬度为82 HD、最大拉伸强度为30.77 MPa、最大断裂伸长率为89.60%,运用Gelprof 518树脂行为分析仪对固化过程进行评价分析,改性后的固化剂活性增加,固化速率提升.综合性能较好的改性固化剂合成条件为m(EP128)∶m(DYTEK-A)∶m(BA)=9∶32∶59,反应温度 50℃,反应时间50 min.这些研究结果有助于深入了解固化剂对环氧树脂固化的影响,并为工业过程中固化剂改性提供了理论依据.
Preparation of modified 2-methylpentanediamine curing agent and its performance
To improve the curing speed and physical properties of curing agents,the curing agent 2-methylpentanediamine(DYTEK-A)was madify using resin epoxy NPEL-128(EP128)and diluted with benzyl alcohol(BA).Different modified curing agents were obtained by varying the amounts used.After mixing the modified curing agents with epoxy resin and curing,the material achieved a maximum hardness of 82 HD,a maximum tensile strength of 30.77 MPa,and a maximum elongation at break of 89.60%.The curing process was evaluated and analyzed using a Gelprof 518 resin behavior analyzer.The activity of the modified curing agent increased,and the curing rate was enhanced.The optimal synthesis conditions for the modified curing agent were m(EP128)∶m(DYTEK-A)∶m(BA)=9∶32∶59,reaction temperature of 50℃,and reaction time of 50 minutes.These research results help to deepen the understanding of the influence of the curing of epoxy resin on curing agents and provide a theoretical basis for the modification of curing agents in industrial processes.

curing agent modificationepoxy resinmechanical propertiesthermosetting behavior

侯森森、徐章燕、胡红兵、闫志国、余响林、梁恩、李留兵、李永汪、彭世琼、唐霞霞

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武汉工程大学化工与制药学院,湖北 武汉 430205

武汉工程大学化学与环境工程学院,湖北 武汉 430205

广州市金永固新材料有限公司,广东 广州 510700

广州麦科凌电力装备有限公司,广东 广州 510900

武汉东昌仓贮技术有限公司,湖北 武汉 430073

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固化剂改性 环氧树脂 力学性能 热固化行为

2024

武汉工程大学学报
武汉工程大学

武汉工程大学学报

影响因子:0.463
ISSN:1674-2869
年,卷(期):2024.46(6)