首页|有序介孔碳负载NiCo2O4电极的制备及其超电容性能

有序介孔碳负载NiCo2O4电极的制备及其超电容性能

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以有序介孔碳(OMC)为载体,采用共沉淀法制备了OMC/NiCo2O4复合物.用X射线衍射(XRD)、傅里叶变换红外(FT-IR)光谱和透射电镜(TEM)研究其结构与形貌,发现NiCo2O4纳米颗粒均匀地负载在有序介孔碳上.循环伏安和恒流充放电测试表明,NiCo2O4质量分数为40%时,在1 A·g-1的电流密度下,复合物电极的比电容可以达到577.0 F·g-1,电流密度为8A·g-1时,比电容可以达到470.8 F·g-1,并具有良好的循环稳定性.在2A·g-1的电流密度下,经过2000次循环后,比电容还可达到508.4 F·g-1,电容保持率为92.7%.
Preparation of Ordered Mesoporous CarbonlNiCo2O4 Electrode and Its Electrochemical Capacitive Behavior
OMC/NiCo2O4 composite was prepared by co-precipitation with ordered mesoporous carbon (OMC) as a support. The crystalline structure and morphology of the composite were investigated by X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and transmission electron microscopy (TEM). TEM images showed that NiCo2O4 was uniformly coated on the OMC. Cyclic voltammetry and galvanostatic charge-discharge were used to investigate the electrochemical performance of the OMC/ NiCo2O4 composite. The specific capacitances of the OMC/NiCo2O4 composite with a mass fraction of 40% NiCo2O4 were 577.0 F G"1 at a current density of 1 A G~' and 470.8 F G~1 at 8 A G-1. The specific capacitance remains at 508.4 F G~1 after 2000 cycles at a current density of 2 A-g~\ with a capacitance retention of 92.7%.

SupercapacitorOrdered mesoporous carbonNiCo2O4Co-precipitation method

车倩、张方、张校刚、卢向军、丁兵、朱佳佳

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南京航空航天大学材料科学与技术学院,南京210016

超级电容器 有序介孔碳 NiCo2O4 共沉淀法

国家然科学基江苏省自然科学基金高等学校博士学科点专项科研基金

20873064BK201103020060287026

2012

物理化学学报
中国化学会

物理化学学报

CSTPCDCSCD北大核心SCI
影响因子:0.951
ISSN:1000-6818
年,卷(期):2012.28(4)
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