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北京市房山区土壤重金属元素分布、富集特征及来源解析

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土壤重金属污染问题日益突出,为了探究北京市房山区土壤重金属含量分布情况,在房山区采集了 152 件表层土壤样品和 240 件深层土壤样品.本文对As、Cd、Cr、Cu、Hg、Ni和Pb这 7 种重金属元素在研究区土壤中的含量分布特征及其富集系数(EF)进行了统计分析,并利用主成因分析(PCA)和正定矩阵因子分解模型(PMF)对元素相关性、来源及贡献率进行了解析.结果表明:As、Cd、Cu、Ni和Pb在研究区的十渡、史家营、霞云岭、蒲洼等地的表层土壤中含量较高,且Cr、Ni和As在周口店、南窖和河北镇等地也有高值点分布,Hg在窦店、阎村、长阳等东部平原区含量较高;土壤中Hg和Cd 富集程度较强,As、Cr、Ni高度相关;土壤中As、Cr、Ni主要来源于自然源(土壤母质),贡献率为73.6%~78.6%,Cd多数来自于人为混合源,贡献率为 83.3%,混合源包括工矿活动、农业活动和交通排放等,Cu、Pb的自然源和混合源占比相近,均为50%左右,Hg主要来源于大气干湿沉降,源贡献率为72.4%.
Distributions,enrichment characteristics,and sources of heavy metals in soils in Fangshan District,Beijing
Heavy metal pollution in soils has become increasingly prominent.To explore the distributions of heavy metals in soils in Fangshan District,Beijing,China,this study collected 152 topsoil samples and 240 deep soil samples from this district.Based on these samples,this study statistically analyzed the distributions and enrichment factors(EF)of seven heavy metal elements,namely As,Cd,Cr,Cu,Hg,Ni,and Pb.Furthermore,this study investigated the correlations,sources,and contribution rates of these ele-ments through principal component analysis(PCA)and positive matrix factorization(PMF).The results show that:① Elements As,Cd,Cu,Ni,and Pb exhibit high contents in the topsoil of the Shidu,Shijiaying,Xiayunling,and Puwa areas.Besides,elements Cr,Ni,and As manifest high contents locally in Zhoukoudian,Nanjiao,and Hebei Town.Element Hg displays high content in the eastern plain areas including Doudian,Yancun,and Changyang;② Elements Hg and Cd are highly enriched,and there exist strong correc-tions among elements As,Cr,and Ni;③ These elements primarily originate from natural sources(soil parent materials),which con-tribute to 73.6%to 78.6%of the elements.Element Cd is mostly sourced from an anthropogenic mixed source,which contributes 83.3%of Cd.The mixed source predominantly consists of industrial and mining activities,agricultural production,and traffic emissions.Elements Cu and Pb showed similar contribution rates of natural and mixed sources,both about 50%.Element Hg in soils primarily stems from dry and wet atmospheric deposition,which yields a contribution rate of 72.4%.

heavy metals in soildistribution characteristicsenrichment degreesourcecontribution rate

韩冰、黄勇、李欢、安永龙

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北京市生态地质研究所,北京 100120

土壤重金属 分布特征 富集程度 来源 贡献率

北京市政府公益性项目&&

11000022T00000043957511000023T000002075084

2024

物探与化探
中国国土资源航空物探遥感中心

物探与化探

CSTPCD
影响因子:0.828
ISSN:1000-8918
年,卷(期):2024.48(3)
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