西安石油大学学报(自然科学版)2025,Vol.40Issue(1) :65-70.DOI:10.3969/j.issn.1673-064X.2025.01.008

适用于高温高盐油藏冻胶堵剂的研制与应用

Research and Application of Gel Plugging Agent for High-Temperature and High-Salt Reservoir

党杨斌 濮兰天 星占龙 贾志伟 马中跃 赵言波 朱卫娜 徐鹿敏
西安石油大学学报(自然科学版)2025,Vol.40Issue(1) :65-70.DOI:10.3969/j.issn.1673-064X.2025.01.008

适用于高温高盐油藏冻胶堵剂的研制与应用

Research and Application of Gel Plugging Agent for High-Temperature and High-Salt Reservoir

党杨斌 1濮兰天 1星占龙 1贾志伟 1马中跃 2赵言波 2朱卫娜 2徐鹿敏2
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作者信息

  • 1. 青海油田油气工艺研究院 采油工艺研究所,甘肃 敦煌 736202
  • 2. 山东石大油田服务股份有限公司,山东 东营 257000
  • 折叠

摘要

针对冻胶类堵剂高温条件下耐温性差的问题,优选了四元疏水缔合型耐温抗盐聚合物(AM/AMPS/DMC/NVP)为主剂,研究了其与多元酚醛树脂交联剂、硫代硫酸钠、纳米二氧化硅反应生成冻胶堵剂的成胶规律.评价了各组分使用浓度、地层水矿化度、温度、剪切程度对成胶性能的影响.实验结果表明,冻胶堵剂在配方浓度范围内均可成胶;矿化度对堵剂成胶强度和封堵性能影响较小;130℃下养护60d后的脱水率小于 10%,堵剂长期热稳定性良好;岩心封堵率大于90%,封堵性能良好;在5 000 r/min条件下,剪切 10 min,成胶性能稳定.最优冻胶堵剂配方为 0.6%聚合物+0.6%多元酚醛树脂交联剂+0.2%硫代硫酸钠+0.3%纳米二氧化硅.该堵剂在青海油田跃 13 块某井上开展了现场试验,堵水后含水下降 23.7%,封堵效果明显.

Abstract

In response to the poor high-temperature resistance of existing gel blocking agents,a gel water plugging agent with high tem-perature and salt resistance is obtained by reaction of the main agent of quaternary hydrophobic associative temperature and salt resistant polymer(AM/AMPS/DMC/NVP),the crosslinking agent of multicomponent phenolic resin,sodium thiosulfate,and nano silica,and its gelation law was studied.The effects of component concentration,formation water salinity,temperature,and shear degree on the gelation performance of it are evaluated.The experimental results indicate that gel can be formed within the concentration range of the formula;The formation water salinity has a relatively small impact on the gel strength and sealing performance of the plugging agent;The dehy-dration rate of the plugging agent after 60 days of curing at 130℃is less than 10%,indicating its good long-term thermal stability;The plugging agent has a plugging rate of over 90%on the rock cores,its plugging performance is good;Sheared at 5 000 r/min for 10 mi-nutes,and the gelation performance of the gel blocking agent is stable.The optimal formula for the gel blocking agent is 0.6%polymer+0.6%multicomponent phenolic resin crosslinking agent+0.2%sodium thiosulfate+0.3%nano silica.The site test result of the plugging agent in a well in Block Yue 13 of Qinghai Oilfield shows that the water cut decreased by 23.7%after plugging.

关键词

堵水/冻胶堵剂/配方/性能评价/高温高盐油藏

Key words

water plugging/gel plugging agent/formulate/performance evaluation/high temperature and high salinity oil reservoirs

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出版年

2025
西安石油大学学报(自然科学版)
西安石油大学

西安石油大学学报(自然科学版)

北大核心
影响因子:0.788
ISSN:1673-064X
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