首页|竹箨基复合相变材料的制备与性能研究

竹箨基复合相变材料的制备与性能研究

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相变材料作为一类具有高能量密度和长周期储热特性的功能性材料,正逐渐成为解决能源储存和利用中关键问题的研究热点,而解决其液相状态下易渗漏的问题对于相变材料工业化发展的进程具有重要意义。考虑到资源的丰富性、可持续性以及潜在的低成本优势,本研究选择竹笋加工剩余物竹箨作为封装相变材料的载体,利用真空浸渍法构建了竹箨基复合相变材料,并通过对其性能的深入分析,揭示其储热特性和潜在应用价值。结果表明,竹箨具有的连续天然多孔网络结构有利于对聚乙二醇(Polyethylene Glycol,PEG)进行封装,其封装效率达到了42。1%,且其与PEG之间仅存在物理相互作用而不会损害PEG的相变特性。复合材料不仅显现出54。3 J/g的融化潜热和54。5 J/g的凝固潜热,竹箨的多孔结构还改善了PEG的过冷现象。此外,所制备的竹箨基复合相变材料具有出色的温度调节、防泄漏、热稳定和可重复使用性,展现了在先进能源相关器件和建筑节能方面的应用潜力。
Preparation and Performance Investigation of Bamboo Sheath-Based Composite Phase Change Materials
Phase change materials,as a class of functional materials with high energy density and long-term heat storage characteristics,are gradually becoming a research focus in addressing key issues in energy storage and utilization.The problem of leakage in their liquid phase state is of significant importance for the industrial development of phase change materials.Considering the abundance of resources,sustainabili-ty,and potential cost advantages,this study selected bamboo culm sheath(bamboo sheath),a byproduct from bamboo shoot processing,as the carrier for encapsulating phase change materials.Utilizing the vacuum impregnation method,a bamboo sheath-based composite phase change material was constructed.Through in-depth analysis of its performance,the study revealed its heat storage characteristics and poten-tial application value.The results indicated that the continuous natural porous network structure of bamboo sheath was conducive to the encapsulation of polyethylene glycol(PEG),achieving an encapsula-tion efficiency of 42.1%.The physical interactions between bamboo sheath and PEG did not compromise the phase change properties of PEG.The composite material exhibited not only a melting latent heat of 54.3 J/g,but also a solidification latent heat of 54.5 J/g.The porous structure of bamboo sheath also im-proved the supercooling phenomenon of PEG.Furthermore,the prepared bamboo sheath-based composite phase change material demonstrated outstanding temperature regulation,leak prevention,thermal stability,and repeatability,showcasing its potential applications in advanced energy-related devices and building energy conservation.

bamboo sheathphase change materialheat storagecomposite material

何林韩、莫雯霞、罗玉芬、刘晓玲、陈松武、陈桂丹、王浏浏

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广西壮族自治区林业科学研究院,广西 南宁 530002

北京林业大学/林业生物质材料与能源教育部工程研究中心,北京 100083

竹箨 相变材料 储热 复合材料

2025

西北林学院学报
西北农林科技大学

西北林学院学报

北大核心
影响因子:1.078
ISSN:1001-7461
年,卷(期):2025.40(1)