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石墨烯负载Pt催化剂的制备及对甲酸的电催化氧化

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采用恒电位电化学还原技术制得石墨烯电极,然后采用循环伏安方法在石墨烯基体上电沉积一层Pt纳米微粒.采用电化学测试技术研究Pt/石墨烯电极材料的电子传递性能及对甲酸电催化氧化性能.相对于商用Pt电极材料,Pt纳米微粒/石墨烯电极材料对甲酸表现出优异的电催化氧化活性,氧化峰电流显著提高.该种石墨烯负载Pt催化剂有望用作直接甲酸燃料电池的优良电极材料.
Preparation of Graphene Supported Pt Catalyst and Its Electrocatalytic Oxidation of Formic Acid
The graphene electrode was prepared by potentiostatic electrochemical reduction technique,and a layer of Pt nanoparticles was deposited on the graphene substrate by cyclic voltammetry.The electron transfer properties of Pt/graphene electrode materials and the electrocatalytic oxidation of formic acid were studied by electrochemical testing technique.Compared with commercial Pt electrode materials,Pt nanoparticles/graphene electrode materials showed excellent electrocatalytic oxidation activity for formic acid,and the oxidation peak current was significantly increased.The graphene-supported Pt catalyst is expected to be used as an excellent electrode material for direct formic acid fuel cells.

graphenedirect formic acid fuel cell(DFAFC)Pt catalystcyclic voltammetryelectrocata-lytic oxidation

陈体伟、田甜、薛茗月、李玉郷、孟成

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许昌学院 化工与材料学院,河南 许昌 461000

石墨烯 直接甲酸燃料电池 铂催化剂 循环伏安法 电催化氧化

河南省大学生创新创业训练计划

202310480046

2024

许昌学院学报
许昌学院

许昌学院学报

影响因子:0.196
ISSN:1671-9824
年,卷(期):2024.43(2)
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