首页|浅谈预应力陶瓷的发展现状

浅谈预应力陶瓷的发展现状

A Review on the Development of Prestressed Ceramics

扫码查看
将预应力增强的方法应用于陶瓷,制得性能优异的预应力陶瓷构件是当前陶瓷领域研究的一大热点.本文从预应力陶瓷的制备方法、增强效果和预应力评价三个方面对当前预应力陶瓷的研究进展进行了总结.结果表明:预应力涂层增强的方法是一种简单、低成本且高效的陶瓷增强方法.通过在陶瓷表层引入压应力,可有效地提高脆性材料的断裂能和抗冲击性能.这主要是因为压应力能够抑制裂纹萌生,提高陶瓷构件的服役寿命.目前,这种方法已成功应用于建筑陶瓷、日用陶瓷、结构陶瓷及功能陶瓷.根据文献报道,预应力Al2O3的弯曲强度比普通Al2O3提高了 37%~39%;预应力ZrO2的弯曲强度比纯ZrO2陶瓷提高了 32%~45%;预应力陶瓷砖的弯曲强度比普通陶瓷砖提高了 50%~102%.对于功能陶瓷,预应力增强的方法被成功应用于固态电解质.在固态电解质表层引入压应力,能够抑制裂纹和枝晶的生长,因此可获得性能可控、高效且力学性能稳定的固态电解质.综上,预应力可显著增强陶瓷的性能.为了阐明预应力陶瓷的增强机理,采用压痕法来研究预应力对裂纹扩展的影响.通过比较预应增强和未增强的陶瓷的裂纹长度和方向,表明预应力的存在形式.此外,采用相对法,计算出预应力的大小.总之,预应力涂层增强法是一种新型、高效的制备技术.这种预应力的设计理论和制备方法同样适用于混凝土领域,因此具有很好的普适性及广阔的应用前景.
The research of prestressed ceramics which fabricated by introducing the prestress in the surface layer of ceramics is a hot topic in the ceramics field.In this work,the research progresses of preparation method,reinforcing effects and the evaluation of residual stress of prestressed ceramics are summarized.Results indicated that prestressed coating reinforcement method was a simple,low-cost and effective way to strengthen ceramics.By introducing residual compressive stress in the surface layer of ceramics,the fracture energy and impact resistance of brittle materials were improved effectively.That was attributed to the compressive stresses can inhibit crack initiation.Thus the service life of ceramic components was extended.Up to now,this method was applied on architectural ceramics,domestic ceramics,structural ceramics and functional ceramics.According to the reported works,the flexural strength of prestressed Al2O3 was increased by about 37%~39%compared to the uncoated Al2O3 ceramics.And the pre-stressed ZrO2 ceramic achieved a flexural strength of 32%~45%higher than that of the common ZrO2 ceramic.While the prestressed porcelain tiles possess a 50%~102%higher flexural strength than that of uncoated counterpart.For the functional ceramics,prestress strengthening method was applied on the preparation of solid electrolyte successfully.Due to the sufficiently high compressive stress in the surface layer of solid electrolyte,cracks and dendrite penetration were restrained.Hence,a controllable,high-performance and mechanically stable solid electrolyte was obtained.Above all,the reinforcing effects of residual stress on ceramics were significantly effective.In order to illuminate the strengthening mechanism of prestressed ceramics,indentation deformation was used to understand the effect of residual stress on crack propagation.By comparing the length and the expanded direction of crack in ceramics with and without coating,the form of residual stress was cleared.In addition,the residual stress can also be determined by using relative method.In general,prestressed coating reinforcement method is a novel and effective preparation technology,which can also be applied in the concrete and the glass fields.The pre-stressing design was universal and has great application prospects.

prestressed ceramicspreparation methodstrengthreinforcing effectsevaluation of residual stress

李海燕、贾志杰、张磊、田远、刘小根、包亦望、万德田

展开 >

中国国检测试控股集团股份有限公司,北京 100024

中国建筑材料科学研究总院有限公司绿色建筑材料国家重点实验室,北京 100024

上海应用技术大学材料学院,上海 201418

预应力陶瓷 制备方法 强度 增强效果 预应力评价

国家重点研发计划国家自然科学基金国家自然科学基金北京市科协青年人才托举工程项目

2021YFB37023005203201152072356

2024

现代技术陶瓷
山东工业陶瓷研究设计院,中国硅酸盐学会特种陶瓷分会

现代技术陶瓷

影响因子:0.22
ISSN:1005-1198
年,卷(期):2024.45(1)
  • 11