现代技术陶瓷2024,Vol.45Issue(1) :169-176.DOI:10.16253/j.cnki.37-1226/tq.2024.01.013

缺碳高熵碳化物(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C1-x硬度的压痕载荷效应

The Indentation Load Effect of Hardness of Non-Stoichiometric High-Entropy Carbides(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C1-x

郭厉威 刘吉轩 秦渊 梁拥成 张国军
现代技术陶瓷2024,Vol.45Issue(1) :169-176.DOI:10.16253/j.cnki.37-1226/tq.2024.01.013

缺碳高熵碳化物(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C1-x硬度的压痕载荷效应

The Indentation Load Effect of Hardness of Non-Stoichiometric High-Entropy Carbides(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C1-x

郭厉威 1刘吉轩 1秦渊 1梁拥成 2张国军1
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作者信息

  • 1. 东华大学纤维材料改性国家重点实验室功能材料研究中心材料科学与工程学院,上海 201600
  • 2. 东华大学理学院,上海 201600
  • 折叠

摘要

本文研究了不同碳空位浓度下的缺碳高熵碳化物陶瓷(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C1-x(HEC1-x,x=0~0.5)硬度的压痕尺寸效应(ISE).实验结果表明,随着载荷从0.05 kgf增加至1 kgf,压痕尺寸快速增大,硬度迅速下降.并且,比例试样阻力(PSR)模型能够较好的描述本研究中缺碳高熵碳化物的压痕尺寸效应.HEC1-x陶瓷的硬度随载荷增大逐渐降低,但其降低幅度随碳空位浓度的升高而先减小后增加,反映出HEC1-x陶瓷的ISE效应随碳空位浓度增加而先减小后增大.HEC0.8的硬度随载荷增加变化最小,其压痕尺寸效应最弱.根据载荷-压痕尺寸关系的拟合曲线计算得出HEC1-x陶瓷的真实硬度随碳空位浓度的升高先增加后减少,在HEC0.9处取得最大值为22.2 GPa.

Abstract

This paper studied the indentation size effect(ISE)of non-stoichiometric high-entropy carbide ceramics(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C1-x(HEC1-x,x=0~0.5)with different carbon vacancy concentration.The experimental results showed that the indentation size increased and the hardness decreased rapidly as the load increased from 0.05 kgf to 1 kgf.Moreover,the proportional specimen resistance(PSR)model can describe the indentation size effect of high-entropy carbides in this study.The hardness decreased gradually with the load rised,but the degree of change decreased first and then increased with the increase of carbon vacancy concentration,which revealed that the ISE in HEC1-x system had the same trend of variation with the increase of carbon vacancy concentration.The hardness of HEC0.8 had the smallest change with the increase of load,indicating it had the weakest ISE.According to the fited polynomial curves of load-indentation size relationship,the true hardness of ceramics increased first and then decreased with the increase of carbon vacancy concentration,and the maximum value was 22.2 GPa at HEC0.9.

关键词

高熵碳化物/碳空位/硬度/压痕尺寸效应

Key words

high-entropy carbides/carbon vacancy/hardness/indentation size effect

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基金项目

中央高校基本科研业务费专项(2232021A-01)

国家自然科学基金(52371023)

国家自然科学基金(52032001)

出版年

2024
现代技术陶瓷
山东工业陶瓷研究设计院,中国硅酸盐学会特种陶瓷分会

现代技术陶瓷

影响因子:0.22
ISSN:1005-1198
参考文献量1
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