首页|气源及纳米颗粒对氟碳-碳氢表面活性剂泡沫性能影响研究

气源及纳米颗粒对氟碳-碳氢表面活性剂泡沫性能影响研究

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以双子短链氟碳表面活性剂(Gemini)和两性碳氢表面活性剂(LAMC)为核心组分制备了环保型泡沫分散体.研究了纳米SiO2颗粒和压缩气源种类对泡沫分散体起泡性、稳定性及铺展特性的影响.结果表明,纳米SiO2颗粒与短链氟碳表面活性剂存在分子间相互作用,在试验范围内,与压缩空气相比,未添加纳米SiO2 颗粒的压缩氮气泡沫高度提升约5.8%,添加浓度为3%的纳米SiO2颗粒后分散体发泡性能略微下降.随着纳米SiO2 颗粒的加入,泡沫的稳定性显著增加,氮气泡沫稳定性比空气泡沫提升约5%.纳米SiO2颗粒形成网状结构聚集体堵塞在Plateau边界中,有效延缓泡沫析液和粗化,从而增强泡沫的稳定性.由于氮气和空气自身密度及对泡沫液膜渗透性的不同,压缩空气泡沫在油面上的平均铺展速率较压缩氮气泡沫提升2.6%.研究结果能够为纳米SiO2 颗粒在环保型泡沫灭火剂的研发和灭火应用方面提供理论指导.
Study on the performance of fluorocarbon-hydrocarbon surfactant foam by gas source and nanoparticles
In this study,environmentally friendly foam disper-sions were prepared using twin-chain fluorocarbon surfactants(Gemini)and amphoteric hydrocarbon surfactants(LAMC)as core components.The influence of nanoscale SiO2 particles and the type of compressed gas on the foaming properties,stability,and spreading characteristics of the foam dispersion were investi-gated.The results revealed that nanoscale SiO2 particles exhibited molecular interactions with short-chain fluorocarbon surfactants,leading to an approximately 5.8%increase in the height of com-pressed nitrogen foam compared to compressed air foam when 3%nanoscale SiO2 particles were added within the experimental range.The foaming performance of the dispersion slightly de-creased after the addition of 3%nanoscale SiO2 particles.How-ever,foam stability significantly increased with the incorporation of nanoscale SiO2 particles,resulting in a 5%improvement in the stability of nitrogen foam compared to air foam.Nanoscale SiO2 particles formed a network-like structure,aggregating within the Plateau borders,effectively delaying foam drainage and coarsen-ing,thereby enhancing foam stability.Due to the inherent differ-ences in density and permeability of foam liquid films between ni-trogen and air,the average spreading rate of compressed air foam on the oil surface increased by 2.6%compared to compressed ni-trogen foam.The findings of this study provide theoretical guid-ance for the development and firefighting applications of environ-mentally friendly foam extinguishing agents containing nanoscale SiO2 particles.

short-chain fluorocarbon surfactantshydrocarbon sur-factantsnanoscale SiO2 particlescompressed gas sourcefoam performance

尚峰举、张佳庆、李开源、李耀强

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国网安徽省电力有限公司电力科学研究院 电力火灾与安全防护安徽省重点实验室(国家电网公司输变电设施火灾防护实验室),安徽 合肥 230601

武汉理工大学 安全科学与应急管理学院,湖北 武汉 430070

应急管理部天津消防研究所,天津 300381

工业与公共建筑火灾防控技术应急管理部重点实验室,天津 300381

天津市消防安全技术重点实验室,天津 300381

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短链氟碳表面活性剂 碳氢表面活性剂 纳米SiO2颗粒 压缩气源 泡沫性能

国家电网安徽省电力公司科技项目

52120523000L

2024

消防科学与技术
中国消防协会

消防科学与技术

CSTPCD北大核心
影响因子:0.846
ISSN:1009-0029
年,卷(期):2024.43(4)
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