首页|18650三元锂电池热失控危险性及燃烧痕迹特征研究

18650三元锂电池热失控危险性及燃烧痕迹特征研究

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为了研究三元锂电池的热失控风险,选取18650镍钴锰三元锂电池为研究对象,搭建电池热失控过程特征参数测量试验平台,探究锂离子电池在不同荷电状态、电滥用、热滥用情况下的热失控过程及燃烧痕迹特征.结果表明:锂电池正极集流板对电池过充、短路发生热失控具有一定的保护作用,荷电量在 25%以上时,电池热失控受损程度与荷电量成正比;可以结合锂离子电池热失控前后电压、温度变化以及电池爆炸燃烧的特征现象,利用温度曲线特征峰判断发生热失控的电池状态,并结合X射线、电压变化来判断电池发生的故障状态,追溯锂电池发生火灾位置.研究成果可为锂电池设计、锂电池火灾扑救以及火灾调查提供参考依据.
Research on the risk of thermal runaway and characteristics of combustion traces of 18650 ternary lithium batteries
In order to study the thermal runaway risk of ternary lithium batteries,18650 nickel cobalt manganese ternary lithium batteries were selected as the research object,and a testing plat-form for measuring the characteristic parameters of battery ther-mal runaway process was built to explore the thermal runaway process and combustion trace characteristics of lithium-ion batter-ies under different states of charge,electrical abuse,and thermal abuse.The results show that the positive current collector plate of lithium batteries has a certain protective effect on thermal run-away caused by overcharging and short circuit of the battery.When the SOC is above 25%,the degree of thermal runaway damage to the battery is directly proportional to the charge.By combining the characteristics of voltage and temperature changes before and after thermal runaway in lithium-ion batteries,as well as the characteristics of battery explosion and combustion,the characteristic peaks of the temperature curve can be used to deter-mine the state of the battery that has experienced thermal run-away,and X-ray and voltage changes can be combined to deter-mine the fault state of the battery and trace the location of the fire in the lithium-ion battery.The research results can provide refer-ence basis for lithium battery design,lithium battery fire extin-guishing,and fire investigation.

nickel cobalt manganese ternary lithium batteryover-chargingthermal runawaytemperatureburning marks

吴俊涛、李芳、杨生魁

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格尔木市金峰路消防救援站,青海 格尔木 816000

青海省消防救援总队,青海 西宁 810000

镍钴锰三元锂电池 过充 热失控 温度 燃烧痕迹

2024

消防科学与技术
中国消防协会

消防科学与技术

CSTPCD北大核心
影响因子:0.846
ISSN:1009-0029
年,卷(期):2024.43(6)
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