首页|正常充电和热滥用共同作用下大容量锂离子电池热失控试验研究

正常充电和热滥用共同作用下大容量锂离子电池热失控试验研究

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以50 Ah大容量三元锂电池为研究对象,采用热失控时间作为电热共同作用工况组合标准,通过改变电池起始SOC和充电倍率,开展了不同场景下正常充电和局部过热共同作用下的电池热失控试验,详细分析了不同场景下电池的热失控时间、燃烧行为、热失控SOC、表面最高温度、温升速率、电压峰值等热电特征参数变化.结果表明,正常充电和热滥用共同作用下,电池起始SOC越高,充电倍率越大,热失控时间越短,热失控剧烈程度由电池热失控SOC决定;电池处于较低SOC时,会在充电过程中发生热失控,电压会在热失控前突增到 10 V以上然后再突降到零,电池处于较高SOC时,共同作用和单一滥用热失控的差异明显减小.
Experimental study on thermal runaway of large-capacity lithium-ion batteries under the combined action of normal charging and thermal abuse
This article focuses on a 50 Ah high-capacity NCM bat-tery as the research object,using thermal runaway(TR)time as the standard for the combination of electric and thermal working conditions.By changing the initial SOC and charging rate of the battery,TR experiments were carried out under the combined ef-fects of normal charging and local overheating in different sce-narios.Changes of thermal and electric parameter characteristics such as TR time,combustion behavior,TR SOC,maximum sur-face temperature,temperature rise rate and voltage peak of the battery in different scenarios were analyzed in detail.The results show that under the combined effect of normal charging and ther-mal abuse,the higher the initial SOC of the battery,the higher the charging rate,and the shorter the TR time.The severity of TR is determined by the battery's TR SOC;When the battery is at a lower SOC,it will experience TR during charging,and the voltage will suddenly increase to over 10 V before TR and then suddenly drop to zero.When the battery is at a higher SOC,the difference between the combined effect and single abuse of TR is significantly reduced.

lithium-ion batteriesthermal runawaynormal charg-ingthermal abuse

张军、何骁龙、王子阳、姚斌

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合肥市消防救援支队,安徽 合肥 230001

中国科学技术大学火灾科学国家重点实验室,安徽 合肥 230026

合肥科大立安安全技术有限责任公司,安徽 合肥 230088

锂离子电池 热失控 正常充电 热滥用

2024

消防科学与技术
中国消防协会

消防科学与技术

CSTPCD北大核心
影响因子:0.846
ISSN:1009-0029
年,卷(期):2024.43(8)
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