消防科学与技术2024,Vol.43Issue(10) :1413-1418.DOI:10.20168/j.1009-0029.2024.10.1413.06

不同释放方式对全氟己酮抑制B类火焰的影响研究

Study on the effect of different release methods on the inhibition of Class B flames by perfluorohexane

韩志跃 任彦博 张信睿 和张航
消防科学与技术2024,Vol.43Issue(10) :1413-1418.DOI:10.20168/j.1009-0029.2024.10.1413.06

不同释放方式对全氟己酮抑制B类火焰的影响研究

Study on the effect of different release methods on the inhibition of Class B flames by perfluorohexane

韩志跃 1任彦博 2张信睿 1和张航1
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作者信息

  • 1. 北京理工大学 爆炸科学与安全防护全国重点实验室,北京 100081
  • 2. 北京理工大学 爆炸科学与安全防护全国重点实验室,北京 100081;枣庄市消防救援支队,山东 枣庄 277100
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摘要

全氟己酮作为一种高效环保的灭火剂,需要依托良好的释放方式才能有效发挥其灭火性能.为了检验不同释放方式下全氟己酮的灭火效能,使用20 mL正庚烷油盘火作为火焰模型,分别利用1.2 MPa的氮气和2 g富氮产气物质来推动全氟己酮释放.讨论和比较了全氟己酮在两种释放方式下,对B类火焰的灭火效果、降温能力和作用机理.研究结果表明:施放的压力对全氟己酮灭火效果影响显著.相比于充装氮气的驱动方式,全氟己酮在富氮产气物质产生的高压气流作用下,能充分释放并及时扑灭火灾,在灭火时间、降温效果、火焰抑制上均有优异的表现.机理分析表明,在1.2 MPa的氮气充装驱动下,大部分的全氟己酮在释放过程中尚未与火焰接触便发生了挥发.而全氟己酮在仅2 g富氮产气物质产生的高压气流作用下,能够与火焰燃烧面充分接触,吸热分解并发挥化学抑制作用,快速阻断燃烧反应.

Abstract

FK-5-1-12,known for its efficiency and cleanliness as a fire extinguishing agent,requires an effective release mode to fully utilize its capabilities.In order to assess the impact of differ-ent release modes on the performance of FK-5-1-12,a 20 mL n-heptane oil pan fire was used as a model for class B flames.The research utilized 1.2 MPa N2 filling and 2 g of nitrogen-rich gas-producing substances(NGS)to facilitate the release of FK-5-1-12.The research focused on comparing and analyzing the fire ex-tinguishing effectiveness,cooling capacity,and mechanisms of FK-5-1-12 on class B flames under these two release modes.The research revealed that application pressure had a significant impact on the fire extinguishing effectiveness of FK-5-1-12.When released through the high-pressure gas flow generated by NGS,FK-5-1-12 showed better performance in extinguishing time,cooling effect,and flame suppression compared to the N2 drive release mode.Mechanistic analysis indicated that a sub-stantial amount of FK-5-1-12 in the 1.2 MPa N2 drive did not reach the flame surface due to volatilization during release.In con-trast,FK-5-1-12 effectively reached the burning surface of the flame with the influence of the high-pressure gas flow produced by only 2 g of NGS.Upon reaching the flame,FK-5-1-12 de-composed by absorbing heat,exerted a chemical inhibition effect,and rapidly halted the combustion reaction.

关键词

全氟己酮/释放方式/B类火焰/灭火性能

Key words

FK-5-1-12/release mode/class B flame/extinguish-ing performance

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基金项目

国家自然科学基金面上项目(22178026)

出版年

2024
消防科学与技术
中国消防协会

消防科学与技术

CSTPCD北大核心
影响因子:0.846
ISSN:1009-0029
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