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集阻燃抗菌于一体的多功能涤棉混纺织物的制备

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本研究使用胶原蛋白与苯基膦酸进行反应,制备了磷氮协效阻燃剂胶原蛋白/苯基膦酸盐(POC).使用浸渍烘干法将其整理到涤棉混纺织物(PTCO)上,详细研究了阻燃整理PTCO的微观形貌、热稳定性能、阻燃性能、燃烧行为、力学性能、抗菌性能及阻燃机理等.扫描电子显微镜图片表明POC均匀地沉积在PTCO的表面.空气氛围下PTCO/POC的Rmax降低了 20.3%,700℃下的残炭由 0.6%提升至 3.3%.PTCO/POC在垂直燃烧中能够自熄,续燃时间与阴燃时间都为0 s,损毁长度为7.8 cm,LOI值为28.2%.在CCT测试中点燃时间由26 s延长至35 s,最大热释放速率与总热释放分别降低了33.8%和 23.6%.此外,PTCO/POC 保留了 88.1%的断裂强力.PTCO/POC对大肠杆菌和金黄色葡萄球菌的抑菌率均达到了99.99%.综上所述,PTCO/POC兼具阻燃性能与抗菌性能.
Preparation of multifunctional polyester cotton blended fabric integrating flame retardancy and antibacterial properties
In this study,a P/N synthesized flame retardant,POC,was prepared by reacting collagen with phosphenylic acid(PPOA),and used to improve the flame retardancy of polyester cotton blended fabrics(PTCO)by the dip‒drying method.A de-tailed study was conducted on the microstructure,thermal stabil-ity,flame retardancy,combustion behavior,mechanical proper-ties,antibacterial properties,and flame‒retardant mechanism of finished PTCO.The scanning electron microscope images indi-cated that POC was uniformly deposited on the surface of PTCO.The Rmax of PTCO/POC under air atmosphere decreased by 20.3%,and the char residues at 700℃increased from 0.6%to 3.3%.PTCO/POC can self‒extinguish,with an afterflame time and afterglow time of 0 s,a damaged length of 7.8 cm,and an LOI value of 28.2%.In cone calorimeter test,the time to ignition was extended from 26 s to 35 s,and the peak heat release rate and total heat release values were decreased by 33.8%and 23.6%,respectively.In addition,the breaking force of PTCO/POC was increased from 725 N of PTCO/PPOA to 810 N,re-maining 88.1%of the breaking force compared with that of PTCO.The antibacterial rates of PTCO/POC against Esch-erichia coli and Staphylococcus aureus both reached 99.99%.In summary,PTCO/POC owned better flame retardancy and anti-bacterial properties.

polyester cotton blended fabricsflame retardancyan-tibacterial propertytensile strength

张丽耀、宋婉萌、刘云

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青岛大学 纺织服装学院,山东 青岛 266071

功能纺织品与先进材料研究院,山东 青岛 266071

新型防火阻燃材料开发与应用国家地方联合工程研究中心,山东 青岛 266071

涤棉混纺织物 阻燃性能 抗菌性能 力学性能

2024

消防科学与技术
中国消防协会

消防科学与技术

CSTPCD北大核心
影响因子:0.846
ISSN:1009-0029
年,卷(期):2024.43(12)