新型建筑材料2024,Vol.51Issue(1) :92-97.

不同粒径氧化镁对磷酸镁水泥水化过程的影响

Effect of different particle size magnesium oxide on hydration process of magnesium phosphate cement

刘泽丰 叶沈豪 刘毅 陈士堃 闫东明 王铁龙
新型建筑材料2024,Vol.51Issue(1) :92-97.

不同粒径氧化镁对磷酸镁水泥水化过程的影响

Effect of different particle size magnesium oxide on hydration process of magnesium phosphate cement

刘泽丰 1叶沈豪 1刘毅 2陈士堃 1闫东明 1王铁龙3
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作者信息

  • 1. 浙江大学建筑工程学院,浙江杭州 310058
  • 2. 浙江大学材料科学与工程学院,浙江杭州 310058
  • 3. 北京特种工程设计研究院,北京 100028
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摘要

磷酸镁水泥(MPC)是一种新型早强快硬胶凝水泥,因其制备方法简单、耐火、耐腐蚀性能优异且无毒环保,受到越来越多的关注.以不同粒径的MgO为原料制备MPC试件,分别从凝结时间、反应热、早期强度、后期强度、孔隙率等方面对MPC的水化硬化过程进行表征,并结合SEM、EDS、XRD和MIP等技术,研究材料微观结构和物质组成的变化.结果表明,随着MgO粒径减小,MPC内部孔隙的孔径减小,MPC早期抗压强度提高,但孔隙率和后期强度呈现先减小后增大的趋势.因此,为控制MPC的水化速率、早期强度和后期强度,选择400目即比表面积为0.52 m2/g的MgO制备MPC试件最为适宜.

Abstract

Magnesium Phosphate Cement(MPC)is a new type of early-strength and fast-hardening cement.It has attracted increasing attention due to its simple preparation method,good fire resistance and corrosion resistance,non-toxic and environmental protection.The MPC samples were prepared with MgO of different particle sizes.The hydration hardening process of MPC was characterized from the aspects of setting time,reaction heat,early strength,late strength and porosity,etc.Scanning electron mi-croscopy(SEM),energy spectrum analysis(EDS),X-ray diffraction(XRD)and porosity analysis(MIP)were employed to study the changes of material microstructure and composition.The results show that with the decrease of MgO particle size,the pore size of the MPC decreases,and the early compressive strength of the MPC increases.However,the porosity and late strength decreased first and then increased with the decrease of MgO particle size.Therefore,in order to control the hydration rate,early strength and late strength of magnesium phosphate material,400 mesh MgO powder with a specific surface area of 0.52 m2/g is the most suitable for MPC sample production.

关键词

氧化镁/磷酸盐/反应热/抗压强度/孔隙率/比表面积

Key words

magnesium oxide/phosphate/heat of reaction/compressive strength/porosity/specific area

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基金项目

山西浙大新材料与化工研究院研发项目(2022SZ-TD006)

出版年

2024
新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
参考文献量24
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