新型建筑材料2024,Vol.51Issue(2) :54-58,67.

特种喷射混凝土用多元胶凝体系缓凝特性研究

Study on retardation of a quaternary cementitious materials system for special shotconcrete

魏凯 徐文冰 张连 沈莎莎 冷勇 朱扬
新型建筑材料2024,Vol.51Issue(2) :54-58,67.

特种喷射混凝土用多元胶凝体系缓凝特性研究

Study on retardation of a quaternary cementitious materials system for special shotconcrete

魏凯 1徐文冰 1张连 1沈莎莎 2冷勇 1朱扬3
扫码查看

作者信息

  • 1. 中交第二航务工程局有限公司,湖北武汉 430040
  • 2. 中国新型建材设计研究院有限公司,浙江杭州 310022
  • 3. 武汉汇跃天聚技术有限公司,湖北武汉 431400
  • 折叠

摘要

研究了常温状态下,不同缓凝剂对复合快硬早强型水泥净浆凝结时间的影响.通过复配复合缓凝剂延缓水泥水化,通过对水泥凝结时间、水化温峰、X射线晶体衍射和扫描电镜分析不同龄期水泥水化产物Ca(OH)2和AFt等生成量的影响,探讨了复合缓凝组分对快硬早强型水泥净浆的缓凝作用机理.结果表明,柠檬酸-硼酸-β-环糊精缓凝体系可以大幅抑制早期C3S水化,由于协同效应,Ca(OH)2生成量的减少和吸附量的增加使水泥浆体中Ca(OH)2浓度大幅降低,有效降低了早期水化速率,具有很好的缓凝效果.

Abstract

The effect of different retarders on the setting time of composite quick-hardening and early-strength cement paste at room temperature was studied.The hydration of cement was delayed by compounding a composite retarder.The products of ce ment hydration at different ages like Ca(OH)2 and AFt were analyzed by the setting time,hydration temperature peak,XRD and SEM.The effect of composite retarder components on the retardation mechanism of cement paste was discussed.The results show that the"citric acid-boric acid-β-cyclodextrin"retarder system can greatly inhibit the early C3S hydration.The reduction of Ca(OH)2 generation and the increase of adsorption amount make the Ca(OH)2 in the cement paste due to the synergistic effect.The con-centration of Ca(OH)2 was greatly reduced,which early hydration rate was effectively reduced and has a good retarding effect.

关键词

四元胶凝体系/复合胶凝材料/复合缓凝剂/水泥水化/凝结时间

Key words

quaternary cementitious system/composite cementitious materials/composite retarder/cement hydration/setting time

引用本文复制引用

出版年

2024
新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
参考文献量14
段落导航相关论文