首页|低热微膨胀水泥制备高强砂浆研究

低热微膨胀水泥制备高强砂浆研究

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低热微膨胀水泥(LHEC)具有低水化热和微膨胀等特性,也是一种低碳型水泥.分别以低热微膨胀水泥和矿渣硅酸盐水泥(PS)制备高强砂浆,设置20、45、70 ℃三种水养护条件,比较研究了2种水泥砂浆在不同水养护温度下的强度和膨胀率,并结合XRD和SEM分析,对相关机制进行了探讨.结果表明:LHEC高强砂浆与PS高强砂浆相比,具有更高的抗折强度、折压比和膨胀率;前者抗折、抗压强度和膨胀率在45℃时最高,而后者抗折、抗压强度在70℃时最高,膨胀率随温度变化不明显.其原因为LHEC高强砂浆中引入了较多的钙矾石相(AFt),水养护温度促进了矿渣的水化及AFt形成,但过高的水养护温度会使AFt向单硫型水化硫铝酸钙相(AFm)转变.
Study of high-strength mortar prepared by low heat expansive cement
Low heat expansion cement(LHEC)is a type of low-carbon cement with low heat of hydration and micro expan-sion properties.The high-strength mortars were prepared with LHEC and Portland-slag cement(PS),and three water curing condi-tions were set at 20,45,70 ℃.The strength and expansion of the mortars at different curing temperatures were compared.Based on XRD and SEM analysis,the related mechanism was discussed.The results show that the high-strength mortars prepared by LHEC have higher flexural strength,flexural-to-compressive ratio and expansion than that prepared by PS.The flexural strength,compressive strength and expansion are highest at 45 ℃for the former,and highest at 70 ℃ for the latter.The expansion of the latter is very small and doesn't changed obviously with temperature.High-strength mortars prepared by LHEC introduces more et-tringite(AFt),and the curing temperature promotes the hydration of slag and the formation of AFt,however causes the transforma-tion of AFt to the calcium sulphoaluminate hydrates(AFm)when it is too high.

Portland cementlow heat expansion cementhigh-strength mortarstrengthexpansion rate

詹早良、金冰欣、章迪、武双磊、徐迅

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浙江鼎峰科技股份有限公司,浙江绍兴 312000

浙江大学材料科学与工程学院,浙江杭州 310027

西南科技大学土木工程与建筑学院,四川绵阳 621010

普通硅酸盐水泥 低热微膨胀水泥 高强砂浆 强度 膨胀率

四川省科技计划

2023YFSY0019

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(3)
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