首页|酶法制备不同分子质量糊精及其对水泥水化的影响

酶法制备不同分子质量糊精及其对水泥水化的影响

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研究酶法制备玉米糊精的工艺条件,采用凝胶渗透色谱法分析玉米糊精的分子质量分布,并且对比了不同分子质量糊精对水泥水化的影响.结果表明,在其他条件一定的情况下,玉米糊精的分子质量(Mw)在只改变酶添加量时为14063~70 948,在只改变反应时间时为12 744~20 526,在只改变反应温度时为14 063~86 179,在只改变淀粉乳质量浓度时为12 635~111 210.一定条件下制备的糊精Mw为48 762,能够在几乎不延长缓凝时间的情况下,使得水化热峰值较空白样降低30%左右.
The effect of different molecular weight dextrins prepared by enzymatic method on cement hydration
Study on the process condition of producing corn dextrin by enzymatic method,and molecular weight distribution was investigated by GPC.And the effects of different molecular weight dextrins on cement hydration were compared.Results indicated that when other conditions were fixed,molecular weight of corn dextrin was changed by α-enzyme dosage from 14 063 to 70 948,by time from 12 744 to 20 526,by temperature from 14 063 to 86 179,by starch concentration from 12 635 to 111210.Un-der certain conditions,a dextrin with an Mw of around 48 762 was prepared,It can reduce the peak hydration heat by about 30%without almost prolonging the retarding time.

corn dextrinGPChigh temperature resistant a-amylasemolecular weight of dextrinscement hydration

茅远、乔敏、陈健、高南箫、单广程、沈斐、吴井志

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高性能土木工程材料国家重点实验室,江苏苏博特新材料股份有限公司,江苏南京 211103

博特新材料泰州有限公司,江苏泰兴 225474

玉米糊精 凝胶渗透色谱法 耐高温α-淀粉酶 糊精分子质量 水泥水化

国家自然科学基金面上项目江苏省自然科学基金江苏省自然科学基金

52178213BK20211030BK20211031

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(3)
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