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粉煤灰对水泥砂浆碳化特性的影响机制

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采用抗压强度、碳化深度、XRD衍射、电子扫描显微镜、红外光谱等研究了加速碳化环境中粉煤灰替代率(等质量替代水泥)对水泥砂浆抗碳化性能和内部微观结构演变的影响.结果表明:水泥砂浆试样的碳化深度随粉煤灰替代率增大而明显加深,抗碳化性能随碳化龄期的延长和粉煤灰替代率的增大而逐渐降低.碳化后氢氧化钙含量明显降低,钙矾石消失,生成方解石和球霰石等碳酸盐晶体.碳化生成的碳酸钙微晶体可以发挥一定的填充作用使浆体微结构更加致密.
Mechanism of influence of fly ash on carbonization characteristics of cement mortar
The influence of fly ash replacement rate(equivalent mass replacement cement)on the carbonation resistance and internal microstructure evolution of cement mortar in an accelerated carbonation environment was studied by using compressive strength,carbonization depth,X-ray diffraction(XRD),scanning electron microscope(SEM)and fourier transform infrared spectrometer(FTIR).The results showed that the carbonation depth of cement mortar samples significantly deepened with the increase of fly ash substitution rate,and the carbonation resistance gradually decreased with the extension of carbonation age and the increase of fly ash substitution rate.After carbonization,the content of Ca(OH)2 decreased significantly,and ettringite disappeared,and calcite and vaterite were formed.The CaCO3 microcrystals produced by carbonization can play a certain filling role to make the microstructure of the slurry more dense.

mortarfly ashcompressive strengthcarbonation depthmicrostructuredurability

马彦涛、史玉柱、杜征宇、李茂森、王露

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中国电力工程顾问集团中南电力设计院有限公司,湖北武汉 430071

武汉大学水资源工程与调度全国重点实验室,湖北武汉 430072

砂浆 粉煤灰 抗压强度 碳化深度 微观结构 耐久性

武汉市科技计划项目中国能源建设股份有限公司重大科技项目

2022022202015028CEEC2021-ZDYF-03

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(6)