新型建筑材料2024,Vol.51Issue(6) :119-123.

新型抗泥聚羧酸减水剂的合成及性能研究

Synthesis and properties of a novel clay-resistant polycarboxylic superplasticizer

薛博文 周婧洁 刘瑜琦 耿涛 孙晋源 梁慧斌
新型建筑材料2024,Vol.51Issue(6) :119-123.

新型抗泥聚羧酸减水剂的合成及性能研究

Synthesis and properties of a novel clay-resistant polycarboxylic superplasticizer

薛博文 1周婧洁 1刘瑜琦 1耿涛 1孙晋源 1梁慧斌1
扫码查看

作者信息

  • 1. 中国日用化学工业研究院,功能性表面活性剂山西省重点实验室,山西太原 030001
  • 折叠

摘要

氯丙烯封端脂肪醇聚氧乙烯醚(AC-AEO9)作为一种可聚合型表面活性剂,具有较大的空间位阻.使用AC-AE09作为抗泥功能单体,制备了新型抗泥聚羧酸减水剂(A-PCE),并考察了功能单体用量对A-PCE分散性和抗泥性的影响,采用X射线衍射仪与比表面与孔径分析仪揭示了A-PCE的抗泥机理.结果表明,在减水剂掺量为0.23%、功能单体与减水剂大单体摩尔比为1∶5的条件下,掺A-PCE的水泥净浆初始、120 min流动度为275、270 mm,减水剂表现出最佳的分散性和抗泥性;由于抗泥功能单体的引入,聚羧酸减水剂具有良好的分散性且在黏土上吸附更少,对黏土的适应性更强.

Abstract

Chloro-propylene terminated fatty alcohol polyoxyethylene ether(AC-AEO9)is a polymerizable surfactant with signifi-cant steric hindrance.A novel anti-clay polycarboxylate polycarboxylic acid superplasticizer(A-PCE)was prepared using AC-AEO9 as functional monomer.The effect of functional monomer dosage on the dispersion and clay resistance of A-PCE was investigated,and the clay resistance mechanism of A-PCE was revealed using X-ray diffraction and specific surface area and pore size analyz-er.The results showed that under the conditions of 0.23%water reducer dosage and the molar ratio of functional monomer to su-perplasticizer macromonomer of 1∶5,the initial and 120 minute flowability of cement slurry mixed with A-PCE were 275 and 270 mm,and the polycarboxylic acid superplasticizer exhibited excellent dispersion performance and mud resistance performance.Due to the introduction of anti-clay functional monomers,polycarboxylate water reducer has good dispersion and less adsorption on clay,making it more adaptable to clay.

关键词

聚羧酸减水剂/功能单体/分子设计/分散性/抗泥性

Key words

polycarboxylate superplasticizer/functional monomer/molecular design/dispersibility/clay resistance

引用本文复制引用

基金项目

自然堂奖学金资助项目(2021)()

出版年

2024
新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
段落导航相关论文