首页|磷石膏的疏水改性研究现状及进展

磷石膏的疏水改性研究现状及进展

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磷石膏是湿法生产磷酸排放的固体废弃物,每生产1t磷酸就会排出约5t磷石膏.磷石膏表面具有亲水性,在高湿度环境下或接触水分之后易出现溶融蠕变效应,对力学性能造成负面影响,限制了其在建筑材料领域中的应用.全面综述了 3种制备疏水磷石膏基材料的方法:表面疏水涂层、内掺疏水剂、有机/无机复合.通过比较各方法的优缺点,发现有机/无机复合能整体提高磷石膏基材料的疏水性和力学性能.
Research status and progress of hydrophobic modification of phosphogypsum
Phosphogypsum(PG)is a solid waste discharged in the production of wet-process phosphoric acid.Nearly 5 tons of phosphogypsum will be discharged for every ton of wet-process phosphoric acid produced.Phosphogypsum surface is hydrophilic,and it is prone to melt creep effect in high humidity environment or after contacting with water,which has a negative impact on mechanical properties and limits its application in building materials field.In this paper,three methods for preparing hydrophobic phosphogypsum-based materials are comprehensively reviewed:surface hydrophobic coating,internal hydrophobic agent and organic/inorganic composite.By comparing the advantages and disadvantages of each method,it is found that organic/inorganic composite can improve the hydrophobicity and mechanical properties of phosphogypsum-based materials as a whole.

phosphogypsumhydrophobicitymodifiedorganic/inorganic composite

李远霞、曾芳芳、杨珖、李燚、陈忠华、何松涛、刘其斌

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贵州大学材料与冶金学院,贵州贵阳 550025

保山职业学院,贵州保山 678000

贵州磷化绿色环保产业有限公司,贵州贵阳 551199

磷石膏 疏水 改性 有机/无机复合

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(7)