首页|氧化镁改性粉煤灰基地聚物用作亚甲基蓝吸附剂的影响研究

氧化镁改性粉煤灰基地聚物用作亚甲基蓝吸附剂的影响研究

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以粉煤灰为原材料,氢氧化钠和水玻璃为激发剂,采用悬浮固化法制备粉煤灰基地聚物(F-GP),同时用氧化镁进行改性,制备氧化镁改性粉煤灰基地聚物(M-GP).研究其对染料亚甲基蓝(MB)的吸附作用,同时研究了吸附时间、MB溶液初始浓度、吸附剂用量和MB溶液pH值对地聚物吸附MB能力的影响,此外,还考虑了 M-GP的可回收性及其染料固定效率.结果表明,M-GP相较于F-GP具有更大的孔径、比表面积以及更好的吸附效果,在最优条件下(m=0.30 g、pH=7、C0=2.5 mg/L、V=50 mL、t=12 h),对MB的去除率达93%,吸附过程遵循Langmuir吸附模型和准二级动力学模型.
Research on the effect of magnesium oxide modified fly ash based polymer as methylene blue adsorbent
Experiments were conducted to prepare fly ash-based mass polymer microspheres(F-GP)using the suspension curing method.Fly ash was used as the raw material,while sodium hydroxide and water glass were used as exciters.Additionally,magnesium oxide-modified fly ash-based polymers(M-GP)were prepared through modification with magnesium oxide(MgO).The adsorption of methylene blue(MB)dye was investigated,and various factors such as adsorption time,initial concentration of MB so-lution,adsorbent dosage,and pH of the MB solution were examined to determine their effects on the adsorption of MB by geopoly-mer.The recoverability of M-GP and its dye immobilization efficiency were also considered.The results revealed that M-GP exhib-ited larger pore size,higher specific surface area,and better adsorption performance compared to F-GP.Under optimal conditions(m=0.30 g,pH=7,C0=2.5 mg/L,V=50 mL,and t=12 h),the adsorption efficiency of M-GP for MB reached 93%.The adsorption pro-cess followed the Langmuir adsorption model and quasi second-order kinetic model.

geopolymerfly ashmodificationMgOadsorption

房立蕾、许峰、马健岩、张如清

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沈阳建筑大学材料科学与工程学院,辽宁沈阳 110168

地聚合物 粉煤灰 改性 氧化镁 吸附

辽宁省教育基金服务地方项目

lnfw201909

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(7)