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亚硝酸根插层镁铝水滑延缓钢筋锈蚀效果及机理

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以碳酸根型镁铝水滑石为原材料,亚硝酸钠为离子交换剂,通过焙烧还原法制备亚硝酸根插层镁铝水滑石(NO2-LDH),以NO2-LDH为阻锈剂,通过盐水干湿循环与全浸泡实验研究了其对HPB300钢筋的缓蚀效果及缓蚀机理.结果表明:随NO2-LDH掺量的增加,盐水干湿循环下钢筋锈蚀面积明显减少;在全浸泡环境下,NO2-LDH使盐溶液中钢筋长时间处于低、中度锈蚀状态,而未掺NO2-LDH盐溶液中的钢筋则处于高锈蚀状态;NO2-LDH与模拟盐锈蚀溶液中的氯离子发生交换吸附并释放出亚硝酸根,是显著延缓钢筋锈蚀的主要原因.
The effect and mechanism of NO2-LDH inhibiting the reinforcement corrosion
Nitrite intercalation magnesium-aluminum hydrotalcite(NO2-LDH)was prepared by roasting and reduction method with carbonate type magnesium-aluminum hydrotalcite as raw material and sodium nitrite as ion exchanger,taking NO2-LDH as rust inhibitov,its corrosion effect and corrosion mechanism on HPB300 reinforced steel are studied by the saline dry and wet circulation and full soaking experiment.The research results show that:with the increase in NO2-LDH,the corrosion area of the steel corrosion under the dry and wet circulation of the saline water is significantly reduced;in the full immersion environment,NO2-LDH uses the steel bars in the simulated salt corrosion solution for a long time in low and moderate corrosive areas,while the steel bars in the simulation salt corrosion solution are not mixed with NO2-LDH and simulation salt in high corrosion areas;the switching and ad-sorption of chloride in the corrosive solution and release nitro root is the main reason why NO2-LDH can significantly delay the corrosion of the reinforcement.

reinforcement corrosionnitrite intercalation hydrotalciteion exchangerust inhibitor

李一帅、宋学锋

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西安建筑科技大学材料科学与工程学院,陕西西安 710055

钢筋锈蚀 亚硝酸根插层水滑石 离子交换 阻锈剂

陕西省科研攻关项目

2018SF-367

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(8)