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改性聚醚引气剂的制备及其对盾构管片混凝土性能的影响

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以顺丁烯二酸酐、多种脂肪酸、不同分子质量的聚乙二醇、苯乙烯磺酸钠、丙烯酰胺等为主要原料制备了改性聚醚引气剂,研究了改性聚醚引气剂和2种常用引气剂(十二烷基硫酸钠、改性松香热聚物)对盾构管片机制砂混凝土性能的影响.结果表明:3种引气剂中,改性聚醚引气剂的起泡效果最佳,泡沫稳定性高且经时损失小,有利于增大混凝土的含气量和坍落度;当引气剂折固掺量均为0.01%时,改性聚醚引气剂可明显改善混凝土内部孔结构,使混凝土的抗压强度、抗水渗透性和抗氯离子渗透性能均有所提高,批量生产的盾构管片质量符合CJJ/T 164-2011循构隧道管片质量检测技术标准》的要求.
Preparation of modified polyether air-entraining agent and its effect on properties of shield segment concrete
Modified polyether air-entraining agent was prepared by maleic anhydride,various fatty acids,polyethylene glycol with different molecular weight,sodium styrene sulfonate and acrylamide,etc.The effects of modified polyether air-entraining agent and two common air-entraining agents(sodium dodecyl sulfate and modified rosin hot polymer)on the properties of shield segment manufactured sand concrete were studied.The results show that the modified polyether air-entraining agent has the best foaming effect,high foam stability and little time loss,and increases the air content and slump of concrete.When the solid content of air-entraining agent is 0.01%,the modified polyether air-entraining agent can obviously improve the internal pore structure of con-crete,and the compressive strength,water permeability resistance and chloride ion permeability resistance of concrete are better than that of the two commonly used air-entraining agents,and the quality of the shield segment applied to the actual mass production meet the requirements of CJJ/T 164-2011"Standard for quality inspection of shield tunnel segment".

shield segmentmanufactured sand concretemodified polyether air-entraining agentpermeabilitypore diameter distribution

李本友、逄鲁峰、刘晓清、赵守民、代龙

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济南轨道中铁管片制造有限公司,山东济南 250214

山东建筑大学土木工程学院,山东济南 250101

盾构管片 机制砂混凝土 改性聚醚引气剂 渗透性 孔径分布

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(8)