新型建筑材料2024,Vol.51Issue(8) :123-129,135.

负温环境下复合磷酸盐对磷酸镁水泥性能的影响

The effect of composite phosphates on the properties of magnesium phosphate cement under negative temperature environment

杨奉源 赖振宇 李军 刘智 蒋俊 卢忠远
新型建筑材料2024,Vol.51Issue(8) :123-129,135.

负温环境下复合磷酸盐对磷酸镁水泥性能的影响

The effect of composite phosphates on the properties of magnesium phosphate cement under negative temperature environment

杨奉源 1赖振宇 2李军 2刘智 2蒋俊 2卢忠远2
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作者信息

  • 1. 西南科技大学环境友好能源材料国家重点实验室,材料与化学学院,四川绵阳 621000;四川蜀道建筑科技有限公司,四川成都 610000
  • 2. 西南科技大学环境友好能源材料国家重点实验室,材料与化学学院,四川绵阳 621000
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摘要

川藏线海拔较高,大部分地区受冰雪灾害影响,混凝土道路易遭受损伤,对修补材料提出了更高的要求.针对严寒环境适应较好的磷酸镁水泥(MPC)存在低温下强度发展较慢的问题,探究了在负温(-5 ℃)环境下,磷酸二氢钾和磷酸二氢钠复合加入对MPC强度、水化特性、微观结构的影响.结果表明,复合掺加磷酸二氢钠可以显著提高MPC的强度,3 h抗压强度达到了 41.2 MPa,相比于纯磷酸二氢钾组提高了 776.6%,28 d抗压强度可达70.0 MPa以上.磷酸二氢钠的加入可促进新的水化产物生成,即Na-Struvite,该水化产物多为无定形或针状,可以有效填充孔隙,细化孔径,有利于强度的提高.

Abstract

The Sichuan-Tibet Highway has high altitudes,and most areas are affected by snow and ice disasters,causing varying degrees of damage to concrete roads,which also poses higher requirements for repair materials.Currently,magnesium phosphate ce-ment(MPC),which adapts well to cold environments,faces the issue of slow strength development at low temperatures.This experi-ment mainly investigates the effects of the combined addition of potassium dihydrogen phosphate and sodium dihydrogen phosphate on the strength,hydration characteristics,and microstructure of magnesium phosphate cement under sub-zero temperatures(-5℃).The results show that the addition of sodium dihydrogen phosphate can significantly improve the strength of magnesium phosphate cement.When fully added,the compressive strength at 3 hours reached 41.2 MPa,which is a 776.6%increase compared to the pure potassium dihydrogen phosphate component of MPC,and the 28-day strength can exceed 70.0 MPa.The addition of sodium dihydrogen phos-phate can promote the formation of new hydration products,namely Na-Struvite,which are mostly amorphous or needle-shaped.These hydration products can effectively fill the pores,refine the pore size,and contribute to the increase in strength.

关键词

磷酸镁水泥/负温环境/磷酸二氢钠/强度

Key words

magnesium phosphate cement/sub-zero environment/sodium dihydrogen phosphate/strength

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基金项目

四川省科技计划项目(2023YFG0379)

出版年

2024
新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
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