首页|固氚用粉煤灰-矿渣基地聚物水泥体系研究

固氚用粉煤灰-矿渣基地聚物水泥体系研究

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针对核工业含氚废水安全处理的难题,构建了一种以碱激发粉煤灰-矿渣为基础的地聚物水泥固化体系.优化设计制备的地聚物水泥固化体具有优异的抗硫酸盐侵蚀、抗冻融性能,且微观结构致密.引入聚丙烯酸极大地增强了纤维与基体间的界面粘结性能,从而有效提高了固化体的抗压和抗折强度.模拟氚水的固化实验研究表明,地聚物水泥固化体的氘渗漏率显著低于传统的普通硅酸盐水泥固化体.地聚物水泥固化体采用聚脲喷涂表面处理后,10%氘水浓度下的喷涂前后氘渗漏率分别为25.11%、0.68%.
Study on fly ash slag based polymer cement system for tritium curing
Aiming at the problem of safe treatment of tritiated wastewater in nuclear industry,a kind of polymer cement curing system based on alkali excited fly ash and slag was established.The cement solidified by optimized design has excellent sulfate re-sistance,freeze-thaw resistance and dense microstructure.The introduction of polyacrylic acid greatly enhanced the interfacial bond between the fiber and the matrix,thus effectively improving the compressive strength and flexural strength of the cured body.Ex-perimental study of simulated tritium water shaws that,the deuterium leakage rate of the polymer cement solidified body in this pa-per is significantly lower than that of the conventional silica cement solidified body.In particular,the deuterium leakage rate before and after spraying at 10%deuterium water concentration is 25.11%and 0.68%,respectively.

fly ash-slaggeopolymer cement curing bodymechanical propertiesdurabilitydeuterium leakage rate

王浚、刘才林、姜力诚、袁丽丽、文旭光

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西南科技大学材料与化学学院,四川绵阳 621010

南宁学院广西中国-东盟综合交通国际联合重点实验室,广西南宁 530000

粉煤灰-矿渣 地聚物水泥固化体 力学性能 耐久性能 氘渗漏率

广西科技计划项目创新驱动发展专项南宁市科学研究与技术开发计划项目

桂科AA2107701120235076

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(9)