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外加组分对碱激发矿渣/粉煤灰胶凝体系强度影响研究

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采用碳酸钠、硫酸钠、硅酸钠、氯化钙、甲酸钙来提升Ca(OH)2-Mg(OH)2复合碱激发矿渣/粉煤灰体系(CMSF)的力学强度,通过X射线衍射、热重分析以及扫描电镜分析了材料的微观产物及结构.结果表明,与空白对照组相比,当碳酸钠掺量为8%时,CMSF各龄期抗压强度提高了 80%左右;当硫酸钠掺量为4%时,CMSF的3、7 d抗压强度分别提高了 79%和90%;当硅酸钠掺量为10%时,CMSF的3、7、28 d抗压强度分别提高了 195%、329%、215%:当氯化钙掺量为10%时,CMSF的3、7、28 d抗压强度分别提高了 375%、402%、248%;当甲酸钙掺量为2%时,CMSF的3、7、28 d抗压强度分别提高了 312%、354%、233%.外加组分会促进C-(A)-S-H凝胶的形成,使微观结构更加致密.
Effect of additives on the strength of alkali activated slag/fly ash cementitious system
Effects of sodium carbonate,sodium sulfate,sodium silicate,calcium chloride,and calcium formate on the mechanical strength of the Ca(OH)2-Mg(OH)2 composite alkali activated slag/fly ash system was studied.The micro-products and structure of the materials were analyzed by X-ray diffraction,thermogravimetric analysis,and scanning electron microscopy.The results showed that compared with the control group without additive,when the sodium carbonate content was 8%,the compressive strength of CMSF at various ages increased by about 80%;When the dosage of sodium sulfate is 4%,the compressive strength of CMSF at 3 and 7 days increased by 79%and 90%,respectively;When the dosage of sodium silicate is 10%,the compressive strength of CMSF at 3,7,and 28 days increased by 195%,329%,and 215%,respectively;When the content of calcium chloride is 10%,the compressive strength of CMSF at 3,7,and 28 days increased by 375%,402%,and 248%,respectively;When the content of calcium formate is 2%,the compressive strength of CMSF at 3,7,and 28 days increased by 312%,354%,and 233%,respectively.Micro-scopic analysis shows that additives can promote the formation of C-(A)-S-H gel,and make the microstructure tend to densify.

alkali activated cementitious materialsadditivesphase compositionmechanical strengthmicrostructure

赵志广、瞿晓玲、贺图升、黎载波、田长安

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韶关学院化学与土木工程学院,广东韶关 512005

碱激发胶凝材料 外加组分 物相组成 力学强度 微观结构

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(11)