首页|EPEG型两性聚羧酸减水剂的合成及性能研究

EPEG型两性聚羧酸减水剂的合成及性能研究

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将六碳高活性大单体乙二醇单乙烯基聚乙二醇醚(EPEG)与丙烯酸(AA)、丙烯酰氧乙基三甲基氯化铵(DAC)、对苯乙烯磺酸钠(SSS)进行四元自由基水溶液聚合反应,得到EPEG型两性聚羧酸减水剂(PCE-EADS),采用FTIR、1H NMR对产物结构进行表征,通过水泥净浆流动度试验和混凝土性能试验测试了 PCE-EADS对水泥的分散性.结果表明,PCE-EADS比普通EPEG型聚羧酸减水剂(PCE-EA)分散性更好,比市售聚羧酸减水剂(Point-S)分散性和保坍性要优,相同条件下掺量比Point-S掺量更少,且混凝土 7、28d抗压强度更高.
Study on synthesis and properties of EPEG type amphoteric polycarboxylate superplasticizer
EPEG type amphoteric polycarboxylate superplasticizer PCE-EADS were synthesized by free radical aqueous solution polymerization reaction of a new type of macromonomer ethylene glycol monovinyl polyethylene glycol ether(EPEG),acrylic acid(AA),acryloyloxyethyl trimethyl ammonium chloride(DAC)and sodium p-styrenesulfonate(SSS)as macromonomer,and the structure of the target product was analyzed and characterized by FTIR and 1H NMR,the dispersion performance of water reducing agents on cement was tested through the flowability of cement slurry and concrete properties.The results show that PCE-EADS has better dispersion than ordinary EPEG type polycarboxylate superplasticizer.PCE-EADS has better dispersion and slump retaining proper-ties than the commercial polycarboxylate superplasticizer product Point-S,and under the same conditions,the dosage is less than that of Point-S,and the compressive strength of concrete at 7 and 28 days is higher.

EPEGamphoteric polycarboxylate superplasticizerfree radical polymerizationdispersionconcrete properties

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中交二公局东萌工程有限公司,陕西 西安 710119

EPEG 两性聚羧酸减水剂 自由基聚合 分散性 混凝土性能

2024

新型建筑材料
中国新型建筑材料工业杭州设计研究院

新型建筑材料

CSTPCD
影响因子:0.569
ISSN:1001-702X
年,卷(期):2024.51(11)