稀有金属(英文版)2024,Vol.43Issue(1) :366-379.DOI:10.1007/s12598-023-02391-0

Attaining synergetic equilibrium of electrical conductivity and tensile strength in GQDs@GN/Cu composites through multi-scale intragranular and intergranular reinforcements

Shuang-Yin Zhang Liang Liu Rui Bao Jian-Hong Yi Sheng-Da Guo
稀有金属(英文版)2024,Vol.43Issue(1) :366-379.DOI:10.1007/s12598-023-02391-0

Attaining synergetic equilibrium of electrical conductivity and tensile strength in GQDs@GN/Cu composites through multi-scale intragranular and intergranular reinforcements

Shuang-Yin Zhang 1Liang Liu 2Rui Bao 1Jian-Hong Yi 1Sheng-Da Guo3
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作者信息

  • 1. Faculty of Materials Science and Engineering,Kunming University of Science and Technology,Kunming 650093,China
  • 2. Faculty of Materials Science and Engineering,Kunming University of Science and Technology,Kunming 650093,China;Key Laboratory of Advanced Materials of Yunnan Province,Kunming University of Science and Technology,Kunming 650093,China
  • 3. Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology,Ganzhou 341000,China
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Abstract

The configuration and quality of reinforce-ments,as well as the robustness of interfacial bonding,holding a critical significance in determining the concur-rence between electrical conductivity and mechanical strength in metal matrix composites.In this study,citric acid was employed as the precursor for synthesizing multi-scale carbon nanomaterials(graphene quantum dots and graphene,abbreviated as GQDs and GN).The GQDs@GN/Cu composites were fabricated through a segmented ball milling process in conjunction with subsequent spark plasma sintering(SPS).The intragranular GQDs and intergranular GQDs@GN had synergistically reinforced Cu composites through Orowan strengthening,load transfer strengthening and refinement strengthening.Furthermore,the robust interface bonding between GQDs@GN and Cu effectively mitigated interfacial impedance stemming from electron-boundary scattering.The yield strength and ulti-mate tensile strength of the GQDs@GN/Cu composites were recorded as 270 and 314 MPa,respectively,repre-senting an improvement of 92 and 28%over pure Cu,while maintaining electrical conductivity at a level comparable to that of pure Cu.This study advances the understanding of the possibility of realizing a synergistic compatibility between electrical conductivity and mechanical strength in Cu composites.

Key words

Cu matrix composites/Interface bonding/Mechanical property/Graphene quantum dots(GQDs)/Electrical conductivity

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基金项目

National Natural Science Foundation of China(52174345)

National Natural Science Foundation of China(52064032)

Science and Technology Major Project of Yunnan Province(202202AG050004)

出版年

2024
稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子:0.801
ISSN:1001-0521
参考文献量40
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