首页|Engineering classification recycling of spent lithium-ion batteries through pretreatment:a comprehensive review from laboratory to scale-up application

Engineering classification recycling of spent lithium-ion batteries through pretreatment:a comprehensive review from laboratory to scale-up application

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The lithium-ion batteries(LIBs)have been widely equipped in electric/hybrid electric vehicles(EVs/HEVs)and the portable electronics due to their excellent electrochemical performances.However,a large number of retired LIBs that consist of toxic substances(e.g.,heavy metals,electrolytes)and valuable metals(e.g.,Li,Co)will inevitably flow into the waste stream,and their incineration or landfill treatment will cause severe risks to ecosystem and human beings.The sustainable and efficient treatment or recycling of valuable resources from spent LIBs should be fully recognized for environmental and resource secu-rity.As one of the most important processes for spent LIBs recycling,the pretreatment is an indispensable step,which is directly related to the subsequent metal extraction and separation processes.Although considerable progresses have been made regarding the pretreatment technologies,there are few summarized reports concerning critical processes of spent LIBs recycling,especially combination of currently available recycling technologies with indus-trialized applications during pretreatments.Therefore,comprehensive review of the current prevailing pretreat-ment technologies in laboratory to existing scale-up applications is quite necessary to reveal cutting-edge development in the field of pretreatment.In this review,the current pretreatment technologies are systematically cate-gorized and introduced,along with critical discussions.This review focused on the various options for pretreat-ment processes itself,instead of general spent LIBs recy-cling technologies without the focused topics that have been sophisticatedly reviewed by previous studies.Here,the deactivation,discharge,dismantling,separation,liber-ation of active material and electrolyte treatment have been summarized with the in-depth discussion of the technology development and current status of each category.Finally,current states of industrial development are also reviewed and discussed for the development of efficient and envi-ronmentally friendly recycling technologies for future applications.This review tends to present a focused topic concerning the pretreatment of spent LIBs to potential readers with a comprehensive illustration of the develop-ment on both cutting-edge technologies and scale-up applications.

Spent lithium-ion batteries(LIBs)RecyclingPretreatmentValuable metalsCutting-edge technologiesIndustrialized application

Shu-Xuan Yan、You-Zhou Jiang、Xiang-Ping Chen、Lu Yuan、Ting-Ting Min、Yu Cao、Wan-Li Peng、Tao Zhou

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Hunan Provincial Key Laboratory of Chemical Power Sources,College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China

College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410083,China

School of Public Policy and Management,Tsinghua University,Beijing 100084,China

China Nonferrous Metal Industry's Foreign Engineering and Construction Co.,Ltd,Beijing 100029,China

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National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaHunan Provincial Science and Technology Plan,China

52074177521743912017TP1001

2024

稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子:0.801
ISSN:1001-0521
年,卷(期):2024.43(3)
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