首页|Novel N-doped multichannel carbon nanofiber architecture with porous CoS nanoprisms for high-performance potassium-ion batteries

Novel N-doped multichannel carbon nanofiber architecture with porous CoS nanoprisms for high-performance potassium-ion batteries

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Potassium-ion batteries(PIBs)have gained significant attention as an alternative to lithium-ion bat-teries(LIBs)due to the abundance of potassium(K)and low cost.Nevertheless,the difficulty in finding appropriate electrode materials that can efficiently store the larger K ions has hindered their practical application.Herein,we report a novel anode material,N-doped multichannel car-bon nanofibers embedded with porous CoS nanoprisms(CSP@NMCNF),for high-performance PIBs.The CSP@NMCNF was synthesized using a two-step strategy comprising of the electrospinning of Co acetate hydroxide nanoprism/binary polymer blend and a subsequent heat treatment.The porous CoS nanoprisms with an anisotropic morphology were well aligned along the length axis of the N-doped multichannel carbon nanofibers,thus ensuring their structural stability during the repeated charge-dis-charge process.In addition,numerous pores facilitated the transport of electrons and ions.Accordingly,the CSP@NMCNF anode exhibited excellent electrochemical performance,delivering a high specific capacity of 368 mAh·g-1 at 0.5 A·g-1 after 200 cycles and excellent rate capability(232 mAh·g-1 at 2.0 A·g-1).

K-ion batteriesCobalt sulfideMultichannel structured compositeElectrospinningNanoprismPorous structure

Jae Bong Lim、Seung-Keun Park

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Department of Advanced Materials Engineering,Chung-Ang University,Gyeonggi-do 17546,Republic of Korea

Department of Intelligence Energy and Industry,Chung-Ang University,Seoul 06974,Republic of Korea

Western Seoul Center,Korea Basic Science Institute,Seoul 03759,Republic of Korea

National Research Foundation of Korea(NRF)from the Korean government(MSIT)

2020R1C1C1003375

2024

稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子:0.801
ISSN:1001-0521
年,卷(期):2024.43(3)
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