首页|Electrolyte effect on electrochemical behaviors of manganese fluoride material for aqueous asymmetric and symmetric supercapacitors

Electrolyte effect on electrochemical behaviors of manganese fluoride material for aqueous asymmetric and symmetric supercapacitors

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Exploring wide voltage window materials is not only an available measure to enhance the energy density of hybrid supercapacitor(HSCs),but also avoids the dynamic mismatch caused by different energy storage mechanisms of two electrodes in assembled symmetrical HSC.How-ever,there are few reports about the wide potential window materials except Bi2O3 and VO2.Therefore,the MnF2 synthesized by solvothermal reaction was served as the electrode for HSC.The MnF2 exhibited electrochemical activity in alkaline solution in three-electrode system,especially with a wide potential window from-0.8 to+0.5 V in 2 mol·L-1 NaOH.Furthermore,the assembled MnF2//MnF2 symmetrical HSC had a potential window of 1.5 V,and it exhibited outstanding long-cycle capability.Meanwhile,when MnF2 was taken as the negative and positive respectively,the potential windows of asymmetric devices CoMoO4//MnF2 and MnF2//Activated Carbon(AC)could reach 1.3 and 1.45 V,respectively,showing excellent cycle stability.This work shows that MnF2 material has great research value in HSC,and provides a new research direction for developing high-performance devices.

Manganese fluoridePotential windowHybrid supercapacitorsElectrochemical performance

Zheng-Hua He、Jian-Fei Gao、Ling-Bin Kong

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State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals,Lanzhou University of Technology,Lanzhou 730050,China

School of Materials Science and Engineering,Lanzhou University of Technology,Lanzhou 730050,China

National Natural Science Foundation of ChinaNational Natural Science Foundation of China

5226104051971104

2024

稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子:0.801
ISSN:1001-0521
年,卷(期):2024.43(3)
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