首页|Vertically grown MoS2 nanosheets on graphene with defect-rich structure for efficient sodium storage

Vertically grown MoS2 nanosheets on graphene with defect-rich structure for efficient sodium storage

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The synthesis of a perpendicular growth struc-ture of MoS2 nanosheets on graphene for efficient sodium storage is challenging yet ideal due to the benefits of open ion diffusion channels and high electronic conductivity.In this study,we have successfully fabricated a novel struc-ture of vertical MoS2 nanosheets on graphene,with ZnS nanoparticles serving as bonding points(MoS2/ZnS/G),through a facile hydrothermal method.During the synthesis process,Zn2+not only acts as a landing site for the vertical growth of MoS2 nanosheets but also triggers the formation of a defect-rich structure in the final samples.This unique architecture of MoS2/ZnS/G effectively combines the advantages of a vertically aligned geometry and a defect-rich structure for energy storage.The resulting structure displays shortened transport paths for electrons/ions,enhanced conductivity,improved structural integrity,and an increased number of active sites for promising electro-chemical performance.As expected,when used as anode for sodium-ion batteries,the as-synthesized MoS2/ZnS/G exhibits excellent rate capability(high capacity of 298 mAh·g-1 at 5 A·g-1)and good cycling stability(a capacity decay of 0.056％per cycle after 500 cycles at 1 A·g-1).According to the kinetic investigations,the electrochemical process of the MoS2/ZnS/G sample is primarily governed by a pseudocapacitive behavior,which enhances the charge/discharge kinetics and allows the MoS2/ZnS/G structure to remain intact during cycling.

MoS2Perpendicular growthGrapheneSodium storageElectrochemical performance

Ying Wang、Jia-Peng He、Han-Qing Pan、Qing-Peng Wang、Lei Zhang、Yong-Chang Liu、Qing-Hong Wang

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School of Chemistry & Materials Science,Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials,Jiangsu Normal University,Xuzhou 221116,China

Institute of Biopharmaceutical Research,Liaocheng University,Liaocheng 252059,China

Centre for Catalysis and Clean Energy,Gold Coast Campus,Griffith University,Gold Coast,QLD 4222,Australia

Beijing Advanced Innovation Center for Materials Genome Engineering,Institute for Advanced Materials and Technology,State Key Laboratory for Advanced Metals and Materials,University of Science and Technology Beijing,,Beijing 10083,China

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Natural Science Foundation of Jiangsu ProvinceNature Science Fundation of Jiangsu Higher Education Institutions of China

BK2021135222KJA430005

2024

10.1007/s12598-023-02447-1

稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子：0.801
ISSN：1001-0521
年,卷(期)：2024.43(3)
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