首页|Rare earth element-modified MOF materials:synthesis and photocatalytic applications in environmental remediation

Rare earth element-modified MOF materials:synthesis and photocatalytic applications in environmental remediation

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Metal-organic framework-like materials(MOFs)have been developed in the fields of photocatalysis for their excellent optical properties and physicochemical properties,including environmental remediation,CO2 photoreduction,water splitting,and so on.With theirimportant roles in various fields,rare earth elements have received growing interests from scientists.Modifying MOFs with rare earth elements for modification allows broadening the absorption spectrum,while the active electrons on their empty 4f orbitals can act as traps to capture photoexcited carriers to inhibit the recombi-nation of electron-hole pairs,thus promoting photocatalytic activity.Therefore,rare earth elements modified MOFs pro-vide an attractive way to achieve their high value utilization.In this mini-review,the synthesis of rare earth element-mod-ified MOFs photocatalysts and corresponding applications in the removal of antibiotics,CO2 reduction,and hydrogen production are constructively summarized and discussed.Finally,the latest advancements and current difficulties of these materials as well as the application prospects are also provided.

Rare earth metalsMOFsPhotocatalytic CO2 reductionEnvironmental remediationWater splitting

Shu-Kun Le、Qi-Jie Jin、Jia-Ao Han、Hua-Cong Zhou、Quan-Sheng Liu、Fu Yang、Jie Miao、Pei-Pei Liu、Cheng-Zhang Zhu、Hai-Tao Xu

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Inner Mongolia Key Laboratory of High-Value Functional Utilization of Low Rank Carbon Resources,Chemical Engineering College,Inner Mongolia University of Technology,Hohhot 010050,China

School of Environmental Science and Engineering,Nanjing Tech University,Nanjing 210009,China

School of Environmental and Chemical Engineering,Jiangsu University of Science and Technology,Zhenjiang 212100,China

Institut National de la Recherche Scientifique-Énergie Matériaux et Télécommunications,Montreal,QC J3X 1P7,Canada

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National Key Research and Development Program of ChinaNational Key Research and Development Program of ChinaNational Key Research and Development Program of ChinaKey R&D Program of Jiangsu ProvinceNational Natural Science Foundation of ChinaNatural Science Foundation of Inner MongoliaJiangsu International Cooperation ProjectNanjing Science and Technology Top Experts Gathering Plan,Natural Science Foundation of Jiangsu ProvincePriority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)Open Foundation of State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control

2021YFB35006002021YFB35006052022YFB3504100BE2022142222081702021BS02016BZ2021018BK20220365SEMPC2023004

2024

10.1007/s12598-023-02584-7

稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子：0.801
ISSN：1001-0521
年,卷(期)：2024.43(4)
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