Abstract
High-cost pre-alloyed powder is the bottleneck problem that limits the widespread application of additive-manufactured shape memory alloys.In this work,the low-cost ternary NiTiFe shape memory alloy is fabricated by laser powder bed fusion(LPBF)technique via mechani-cally mixed pre-alloy NiTi powder and varying contents pure Fe powder(1,2,3 wt%).All NiTiFe alloys show a relative density of up to 99.8%by optimizing the LPBF processing parameters.Owing to the heterogeneous nucleation effect of micron-sized Fe particles,both grain refinement and texture weakening are generated in the NiTiFe alloys,accompanied by the reduction of dislocation density.For the room-temperature mechanical properties,the NiTi-3Fe alloy shows the highest microhardness of HV 370,but the fracture strength and elongation reduce to 1701 MPa and 23%simultaneously.The evolution of mechanical properties is attributed to the high internal defects,low dislocation density and the incoherent oxide.Moreover,the NiTi-3Fe alloy shows the quasi-linear superelasticity behavior;the superelastic recoverable strain of NiTi-1Fe and NiTi-2Fe decreased with the increase in Fe content.This study provided a new-fangled insight for the development of multi-component NiTi-based shape memory alloys by additive manufacturing.
基金项目
National Natural Science Foundation of China(52201225)
Postdoctoral Foundation Project of Shenzhen Polytechnic(6021330013K0)
Additive Manufacturing Technology R&D Center(602331004PQ)
Guangdong Provincial General University Innovation Team Project(2020KCXTD047)
Shenzhen science and Technology Innovation Commission(JSGG20200701095008016)
Shenzhen Science and Technology Program(RCBS20221008093241051)
Natural Science Foundation of Guangdong Province(2022A1515110389)