稀有金属(英文版)2024,Vol.43Issue(6) :2730-2738.DOI:10.1007/s12598-024-02620-0

FeNi Prussian blue analogues on highly graphitized carbon nanosheets as efficient glucose sensors

Jin-Hang Xue Qiu-Hong Sun Cheng Han Yuan-Dong Yang Shao-Jie Xu Qi-Peng Li Jin-Jie Qian
稀有金属(英文版)2024,Vol.43Issue(6) :2730-2738.DOI:10.1007/s12598-024-02620-0

FeNi Prussian blue analogues on highly graphitized carbon nanosheets as efficient glucose sensors

Jin-Hang Xue 1Qiu-Hong Sun 2Cheng Han 2Yuan-Dong Yang 1Shao-Jie Xu 2Qi-Peng Li 3Jin-Jie Qian2
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作者信息

  • 1. College of Life and Environmental Science,Wenzhou University,Wenzhou 325000,China;College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325000,China
  • 2. College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325000,China
  • 3. College of Chemistry and Chemical Engineering,Zhaotong University,Zhaotong 657000,China
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Abstract

Meeting the continuous glucose monitoring requirements of individuals necessitates the research and development of sensors with high sensitivity and stability.In this study,a straightforward strategy was proposed for synthesizing ultra-thin oxygen-rich graphitized carbon nanosheets(denoted as GCS-O).These nanosheets are obtained by calcining a topologically two-dimensional indium-based coordination polymer.Subsequently,the growth of FeNi Prussian blue analogue(PBA)on GCS-O effectively introduces active sites and increases the nitro-gen content within the carbonaceous matrix.The resulting FeNi-PBA/GCS-O composite exhibits excellent glucose sensing performance with a broad linear range of 1 to 1300μmol·L-1.Meanwhile,it also achieves a high sensitivity of 2496 μA·mmol-1·L·cm-2,a limit of detection of 100 nmol·L-1(S/N=3),and commendable long-term dura-bility.The relatively simple synthesis process,exceptional sensitivity,and satisfactory electrochemical sensing per-formance of FeNi-PBA/GCS-O open up new directions for biosensor applications.

Key words

Coordination polymer/Carbon nanosheet/Prussian blue analogue/Surface reconstruction/Glucose oxidation

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基金项目

国家自然科学基金(21601137)

浙江省自然科学基金(LQ16B010003)

Basic Science and Technology Research Project of Wenzhou,Zhejiang Province(H20220001)

Special Basic Cooperative Research Programs of Yunnan Provincial Undergraduate Universities Association(202101BA070001-042)

Yunnan Province Young and Middleaged Academic and Technical Leaders Reserve Talent Project(202105AC160060)

出版年

2024
稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDCSCDEI
影响因子:0.801
ISSN:1001-0521
参考文献量31
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