Abstract
Meeting the continuous glucose monitoring requirements of individuals necessitates the research and development of sensors with high sensitivity and stability.In this study,a straightforward strategy was proposed for synthesizing ultra-thin oxygen-rich graphitized carbon nanosheets(denoted as GCS-O).These nanosheets are obtained by calcining a topologically two-dimensional indium-based coordination polymer.Subsequently,the growth of FeNi Prussian blue analogue(PBA)on GCS-O effectively introduces active sites and increases the nitro-gen content within the carbonaceous matrix.The resulting FeNi-PBA/GCS-O composite exhibits excellent glucose sensing performance with a broad linear range of 1 to 1300μmol·L-1.Meanwhile,it also achieves a high sensitivity of 2496 μA·mmol-1·L·cm-2,a limit of detection of 100 nmol·L-1(S/N=3),and commendable long-term dura-bility.The relatively simple synthesis process,exceptional sensitivity,and satisfactory electrochemical sensing per-formance of FeNi-PBA/GCS-O open up new directions for biosensor applications.
基金项目
国家自然科学基金(21601137)
浙江省自然科学基金(LQ16B010003)
Basic Science and Technology Research Project of Wenzhou,Zhejiang Province(H20220001)
Special Basic Cooperative Research Programs of Yunnan Provincial Undergraduate Universities Association(202101BA070001-042)
Yunnan Province Young and Middleaged Academic and Technical Leaders Reserve Talent Project(202105AC160060)