稀有金属(英文版)2024,Vol.43Issue(6) :2769-2783.DOI:10.1007/s12598-023-02592-7

Carbon nanofibers embedded with Fe-Co alloy nanoparticles via electrospinning as lightweight high-performance electromagnetic wave absorbers

Wen-Jun Cai Jian-Guo Jiang Zi-Dong Zhang Zi-Xuan Liu Lu-Jie Zhang Zhen-Kun Long Ke Bi
稀有金属(英文版)2024,Vol.43Issue(6) :2769-2783.DOI:10.1007/s12598-023-02592-7

Carbon nanofibers embedded with Fe-Co alloy nanoparticles via electrospinning as lightweight high-performance electromagnetic wave absorbers

Wen-Jun Cai 1Jian-Guo Jiang 2Zi-Dong Zhang 1Zi-Xuan Liu 1Lu-Jie Zhang 1Zhen-Kun Long 1Ke Bi3
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作者信息

  • 1. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials(Ministry of Education),Shandong University,Jinan 250061,China;School of Materials Science and Engineering,Shandong University,Jinan 250061,China
  • 2. Energy Institute,Qilu University of Technology(Shandong Academy of Sciences),Jinan 250014,China
  • 3. State Key Laboratory of Information Photonics and Optical Communications,School of Science,Beijing University of Posts and Telecommunications,Beijing 100876,China
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Abstract

As a lot of electromagnetic pollution and interference issues have emerged,to overcome electro-magnetic interference,prevent electromagnetic hazards,and develop new high-performance electromagnetic wave(EMW)absorbers have become a significant task in the field of materials science.In this paper,a three-dimensional(3D)carbon nanofibers network with core-shell structure,embedded with varied molar ratios of iron and cobalt(4∶0,3∶1,2∶2,1∶3,0∶4),was effectively synthesized(Fe/Co@C-CNFs)via electrospinning.The phase,microstructure,magnetic and EMW absorption properties were studied.It is discovered that Fe/Co@C-CNFs doped with iron:cobalt=1∶1 have excellent EMW absorption capacity.When the matching thickness is 1.08 mm,the minimum reflection loss(RL)value is-18.66 dB,while the maxi-mum effective absorption bandwidth(EAB)reaches 4.2 GHz(13.9-18 GHz)at a thickness of 1.22 mm.This is owing to the absorbers'superior impedance matching and multiple reflections as well as the conductivity,dielectric,and magnetic losses of carbon nanofibers embedded with Fe-Co alloy particles.In addition,the radar cross section(RCS)of the absorbers has been calculated by CST Studio Suite,showing that the absorbing coating can effectively reduce the RCS at various angles,especially for Fe/Co@C-CNFs doped with iron:cobalt=1∶1.These findings not only provide new insights for the preparation of light-weight and high-performance electromagnetic wave absorbers,but also contribute to energy storage and conversion.

Key words

Electromagnetic wave(EMW)absorbers/Fe/Co@C-CNFs/Core-shell structure/EMW absorbing mechanism/Radar cross section(RCS)

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基金项目

国家自然科学基金(52272117)

国家重点研发计划(2022YFB3505104)

国家重点研发计划(2022YFB3706604)

山东省重点研发计划(2022TSGC2322)

出版年

2024
稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子:0.801
ISSN:1001-0521
参考文献量71
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