稀有金属(英文版)2024,Vol.43Issue(9) :4162-4197.DOI:10.1007/s12598-024-02705-w

Electrolytes additives for Zn metal anodes:regulation mechanism and current perspectives

Yu-Zhe Zhang Huai-Sheng Ao Qi Dong Shao-Jie Zhang Zhi-Guo Hou Na-Na Wang Xue-Song Xie Jian Rong Zhong-Yu Li
稀有金属(英文版)2024,Vol.43Issue(9) :4162-4197.DOI:10.1007/s12598-024-02705-w

Electrolytes additives for Zn metal anodes:regulation mechanism and current perspectives

Yu-Zhe Zhang 1Huai-Sheng Ao 2Qi Dong 3Shao-Jie Zhang 3Zhi-Guo Hou 3Na-Na Wang 4Xue-Song Xie 5Jian Rong 1Zhong-Yu Li6
扫码查看

作者信息

  • 1. School of Environmental Science and Engineering,Changzhou University,Changzhou 213164,China
  • 2. School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
  • 3. Hefei National Laboratory for Physical Science at Microscale,School of Chemistry and Materials Science,University of Science and Technology of China,Hefei 230026,China
  • 4. Institute for Superconducting and Electronic Materials,Australian Institute for Innovative Materials,Innovation Campus,University of Wollongong,North Wollongong,NSW 2500,Australia
  • 5. Department of Chemical and Materials Engineering,University of Alberta,Edmonton AB T6G 1H9,Canada
  • 6. School of Environmental Science and Engineering,Changzhou University,Changzhou 213164,China;School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
  • 折叠

Abstract

With distinct advantages such as high gravi-metric and volumetric capacity(5855 mAh·cm-3 and 820 mAh·g-1),low redox potential(-0.762 V vs.standard hydrogen electrode(SHE)),high abundance,low toxicity and intrinsic safety of Zn metal anode,Zn-ion batteries have become a potential alternative to Li-ion batteries.However,several challenges still need to be addressed prior to the practical applications of Zn-ion batteries,such as dendrite growth during Zn plating/stripping and interfacial side reactions on the Zn surface.Such issues can be addressed by introducing additives to regulate the components and structures of the electrolyte.In this review,we systematically discussed the core issues of metallic Zn anodes and comprehensively summarized a novel perspective of the regulation mechanism of inhibit-ing dendrite growth or interfacial side reactions in Zn anodes by introducing additives into aqueous electrolytes.Furthermore,some discussions and prospects for aqueous Zn ion batteries(AZIBs)are presented for future research.

Key words

Electrolyte additives/Zn metal anode/Regulation mechanism/Current perspectives/AZIBs

引用本文复制引用

基金项目

National Natural Science Foundation of China(21831006)

National Natural Science Foundation of China(21975244)

National Natural Science Foundation of China(22278042)

National Natural Science Foundation of China(22008014)

Research Initiation Fee of Changzhou University(ZMF23020030)

Changzhou Young Scientific and Technological Talents Promotion Project()

Qing Lan Project of Jiangsu Province and the Science and Technology Project of Changzhou City(CJ2022002)

Introduction and Cultivation of Leading Innovative Talents Foundation of Changzhou,Jiangsu Province(CQ20220093)

出版年

2024
稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDCSCDEI
影响因子:0.801
ISSN:1001-0521
参考文献量4
段落导航相关论文