稀有金属(英文版)2024,Vol.43Issue(11) :5994-6005.DOI:10.1007/s12598-024-02850-2

Circumventing brittleness of 3D-printed Al2O3 cellular ceramic structures via compositing with polyurea

Xue-Qin Zhang Ru-Yue Su Xiong Gao Jing-Yi Chen Guo Liu Ru-Jie He Ying Li
稀有金属(英文版)2024,Vol.43Issue(11) :5994-6005.DOI:10.1007/s12598-024-02850-2

Circumventing brittleness of 3D-printed Al2O3 cellular ceramic structures via compositing with polyurea

Xue-Qin Zhang 1Ru-Yue Su 1Xiong Gao 1Jing-Yi Chen 1Guo Liu 2Ru-Jie He 1Ying Li1
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作者信息

  • 1. Institute of Advanced Structure Technology,Beijing Institute of Technology,Beijing 100081,China
  • 2. Department of Mechanical Engineering,City University of Hong Kong,Hong Kong 999077,China
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Abstract

Benefiting from excellent mechanical properties and low density,cellular ceramic structures(CCSs)are competitive candidates as structural components.However,inherent brittleness from strong chemical bonds among atoms extremely impeded CCSs'application.Natural materials occupied outstanding strength and toughness simultaneously due to the dual-phase interpenetrated structure.Inspired by natural materials,it was proposed to fabricate coating covered and fulfilled polyurea/CCS interpenetrated composites(C/CCSs and B/CCSs)to cir-cumvent the brittleness of 3D-printed Al2O3 CCSs.It was demonstrated that polyurea coating had less effect on the compressive strength of C/CCSs but tremendously improved their energy-absorbing ability.The energy-ab-sorbing ability of C/CCSs was improved from 26.48-52.57 kJ·m-3 of CCSs to 1.04-1.89 MJ.m-3 because of the extended plateau stage.Furthermore,com-pressive strength and energy-absorbing ability of B/CCSs were strengthened to 1.33-1.36 and 2.84-4.61 times of C/CCSs,respectively.Besides,failure mode of C/CCSs changed from localized deformation to fracturing entirely with the increase in relative density of CCSs inside,which was the same as that of CCSs.However,with the help of polyurea coating,C/CCSs were still intact at strains up to 60%,which would never fail catastrophically as CCSs at low strains.B/CCSs tended to fracture as a whole,which was not influenced by relative density of pristine CCSs.It was believed that this work provided a creative way to circumvent the brittleness of CCSs and improve their mechanical performances.

Key words

Cellular ceramic structures/Dual-phase interpenetrated composites/Energy-absorbing ability/Compressive strength/3D printing

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出版年

2024
稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子:0.801
ISSN:1001-0521
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