稀有金属(英文版)2024,Vol.43Issue(11) :6054-6067.DOI:10.1007/s12598-024-02947-8

Enhanced strength of a high-conductivity Cu-Cr alloy by Sc addition

Tao Huang Chao-Min Zhang Ying-Xuan Ma Shu-Guo Jia Ke-Xing Song Yan-Jun Zhou Xiu-Hua Guo Zhen-Peng Xiao Hui-Wen Guo
稀有金属(英文版)2024,Vol.43Issue(11) :6054-6067.DOI:10.1007/s12598-024-02947-8

Enhanced strength of a high-conductivity Cu-Cr alloy by Sc addition

Tao Huang 1Chao-Min Zhang 1Ying-Xuan Ma 2Shu-Guo Jia 1Ke-Xing Song 3Yan-Jun Zhou 1Xiu-Hua Guo 2Zhen-Peng Xiao 2Hui-Wen Guo4
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作者信息

  • 1. School of Materials Science and Engineering,Henan University of Science and Technology,Luoyang 471023,China;Henan Key Laboratory of Non-Ferrous Materials Science and Processing Technology,Luoyang 471023,China
  • 2. School of Materials Science and Engineering,Henan University of Science and Technology,Luoyang 471023,China
  • 3. School of Materials Science and Engineering,Henan University of Science and Technology,Luoyang 471023,China;Henan Key Laboratory of Non-Ferrous Materials Science and Processing Technology,Luoyang 471023,China;Henan Academy of Sciences,Zhengzhou 450046,China;Henan Key Laboratory of Advanced Conductor Materials,Zhengzhou 450046,China
  • 4. Chinaclo Luoyang Copper Processing Co.Ltd.,Luoyang 471023,China
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Abstract

A new Cu-Cr-Sc alloy was designed,prepared and subjected to deformation heat treatment.Transmission electron microscopy(TEM),electron backscatter diffrac-tion(EBSD)and X-ray diffraction(XRD)were employed to investigate the effects of Sc on the microstructural changes in the Cu-Cr alloy in different states,examine the changes in the precipitates during aging,reveal the intrinsic correlation between the structure and property in the peak aging state,and evaluate the Sc distribution in the Cu-Cr alloy.The addition of Sc significantly increased the yield strength of the Cu-Cr alloy by~24.6%after aging at 480 ℃ for 1 h,while it had a high electrical conductivity of 81.5%international annealed copper standard(IACS).This enhancement was attributed to the effective inhibition of Cr phase coarsening and recrystallization through the addition of Sc,which strengthened the alloy.Furthermore,in the Cu-Cr-Sc alloy,most of the Sc atoms precipitated as the Cu4Sc phase,with a small amount of Sc segregating at the grain boundaries to pin them.This grain boundary pinning helped to inhibit grain growth and further improve the strength.The main strengthening mechanisms identified in Cu-Cr-Sc alloys were dislocation strengthening and pre-cipitation strengthening.

Key words

Cu-Cr-Sc alloy/High strength and high conductivity/Precipitation strengthening/Cr precipitates

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出版年

2024
稀有金属(英文版)
中国有色金属学会

稀有金属(英文版)

CSTPCDEI
影响因子:0.801
ISSN:1001-0521
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