首页|表面氟化g-C3N4光催化降解罗丹明B的性能研究

表面氟化g-C3N4光催化降解罗丹明B的性能研究

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以三聚氰胺为前驱体制备g-C3N4(缩写为CN),采用不同体积的氢氟酸(HF)对CN进行表面氟化.通过X-射线粉末衍射(XRD)、冷场发射扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)、紫外-可见漫反射吸收(UV-Vis DRS)等对样品的结构、形貌以及光电化学性质进行分析测试.在紫外光下降解罗丹明B(RhB),探究表面氟化对CN的光催化降解RhB性能影响.结果表明,表面氟化可以改变CN表面电子结构,促进光生载流子的分离和传输,从而提升其光催化性能.在优化的实验条件下,CN-0.2F样品对RhB的降解率可达47.9%,是CN光降解率的1.6倍.
Reinforcing the Photocatalytic Degradation of Rhodamine B Through the Surface Fluorination of g-C3N4
g-C3N4(denoted as CN)was prepared using melamine as precursor system,and then treated with different volumes of HF to prepare fluorinated CN surface.The structure,morphology and electrochemical properties of the samples were characterized by XRD,SEM,FT-IR and UV-Vis DRS.The effects of surface fluorination on CN over the UV light induced photocatalytic degradation of rhodamine B(RhB)were preliminarily investigated.The results indicate that the surface electronic structure of CN can be rationally tuned by fluorine ions,thereby boosting the separation and transport of photoinduced charge carriers,ultimately enhancing the photocatalytic performance.Under optimized experimental conditions,the degradation rate of RhB by CN-0.2F sample can reach 47.9%,which is 1.6 times that of pure CN counterpart.

carbon nitridesurface fluoridationphotocatalysisrhodamine B

刘小刚、张欣、陈梦雨、李艳艳、兰玉典

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信阳师范大学化学化工学院,河南信阳 464000

氮化碳 表面氟化 光催化 罗丹明B

国家自然科学基金项目信阳师范学院"南湖学者奖励计划"青年项目

21902140

2024

信阳师范学院学报(自然科学版)
信阳师范学院

信阳师范学院学报(自然科学版)

CSTPCD
影响因子:0.446
ISSN:1003-0972
年,卷(期):2024.37(1)
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