首页|钒离子改性MXene的制备及其在锂硫电池中的应用研究

钒离子改性MXene的制备及其在锂硫电池中的应用研究

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利用化学刻蚀后得到的 MXene(MX)片层具有大量阴离子官能团的特点,采用喷雾干燥技术,设计并合成了钒离子改性 MXene(MX-VN)材料用于锂硫电池正极.MXene的优异导电性可以提高硫正极整体的导电性,同时原位构建的 MX-VN界面可以提高对多硫化物的吸附效果和催化能力,提高硫的利用率.实验结果表明,采用 MX-VN/S为正极的锂硫电池在0.1 C下的放电容量高达1438 mAh/g,且在0.5 C下循环200次以后容量保持率高达77.5%,电池性能明显提升.
Preparation of MXene Modified by Vanadium Ion and Their Application in Lithium-Sulfur Batteries
The MXene(MX)sheet obtained by chemical etching has a large number of anionic functional groups.Based on the spray drying technology,the MXene modified by vanadium ion(MX-VN)material was designed and synthesized for the cathode of lithium-sulfur batteries(LSBs).The excellent conductivity of MXene could improve the overall conductivity of the sulfur cathode.At the same time,the in-situ constructed MX-VN interface could improve the adsorption effect and catalytic ability of polysulfides,meanwhile improve the utilization rate of sulfur.The experimental results showed that the discharge capacity of the LSBs with MX-VN/S as the cathode was as high as 1438 mAh/g at 0.1 C,and the capacity retention rate was as high as 77.5%after 200 cycles at 0.5 C.The performance of the battery was significantly improved.

lithium sulfur batteriesMXenevanadium nitrideshuttle effect

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河南省信阳生态环境监测中心,河南 信阳 464000

锂硫电池 MXene 氮化钒 穿梭效应

国家自然科学基金

516022756

2024

信阳师范学院学报(自然科学版)
信阳师范学院

信阳师范学院学报(自然科学版)

CSTPCD
影响因子:0.446
ISSN:1003-0972
年,卷(期):2024.37(2)
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