首页|光伏多晶硅定向凝固不平衡散热的数值研究与实验

光伏多晶硅定向凝固不平衡散热的数值研究与实验

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定向凝固是物理法提纯光伏多晶硅的重要工艺方法.为改进传统定向凝固一维散热产生较大热应力和应变的缺点,提出一种新型不平衡散热结构和工艺方案,利用特定热阻设计和散热通道来降低热应力和应变.采用ProCAST软件对一维散热与不平衡散热进行三维数值建模,通过对比表明,不平衡散热方案较一维散热,热应力平均降幅可达52.56%,平均凝固速率增长20.67%,凝固时间减少17.10%,并且能在非一维温度场中保持相变界面的稳定.采用YITIPV型真空铸锭炉和3303工业硅原料,进行大尺寸铸锭(1 m×1 m× 0.3 m)对照实验.实验证明,不平衡散热方案可以提高凝固速率和成品质量,制备的硅锭顶部更平整,实际总凝固时间减少15.75%,提纯单位重量硅的能耗降低17.86%,铸锭裂纹更少,有效体积更大.样片分析还表明,硅片平均电阻率提高7.86%,B、P、Al三种元素的杂质含量分别降低了 28.6%、15.2%和83.3%.实验不但证实了不平衡散热结构和工艺的有效性,也验证了数值模型的适配性.该新型结构和工艺提高了铸锭质量和生产效率,降低了裂锭风险和成本,具备推广应用价值.
Numerical Study and Experiment of Unbalanced Heat Dissipation Method in Directional Solidification of Photovoltaic Polysilicon
Directional solidification(DS)was an important process for physical purification of photovoltaic polysilicon.In order to improve the defect of large thermal stress and strain caused by one-dimensional heat dissipation in directional solidification,a innovative unbalanced heat dissipation structure and process were proposed,which used specific thermal resistance designs and heat dissipation channels to reduce thermal stress and strain.Using ProCAST software,three-dimensional numerical modeling of one-dimensional heat dissipation and unbalanced heat dissipation was carried out.The comparison results shows that compared with one-dimensional heat dissipation,the unbalanced heat dissipation scheme can reduce the average thermal stress by 52.56%,increase the average solidification rate by 20.67%,reduce the solidification time by 17.10%,and maintain the stability of the phase change interface in the non-one-dimensional temperature field.Using the YITIPV type vacuum ingot furnace and 3303 industrial silicon raw materials,a large-size ingot(1 mxl mx0.3 m)control experiment was carried out.The experiment proved that the unbalanced heat dissipation scheme can improve the solidification rate and product quality,the top of the prepared silicon ingot is flatter,the actual total solidification time is reduced by 15.75%,the energy consumption per unit weight of silicon is reduced by 17.86%,the ingot cracks are less,and the effective volume is larger.The sample analysis also shows that the average resistivity of the silicon wafer increase by 7.86%,and the impurity content of the three elements B,P,and Al decrease by 28.6%,15.2%,and 83.3%,respectively.The experiment not only confirm the effectiveness of the unbalanced heat dissipation structure and process but also verify the adaptability of the numerical model.This new structure and process improve the quality and production efficiency of ingots,reduce the risk and cost of ingot cracking,and have promotion and application value.

PolysiliconDirectional solidificationUnbalanced heat dissipation methodThermal stressnumerical modeling

朱徐立、谢连发、黄丹辉、陈民恺

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厦门城市职业学院交通工程学院,厦门 361008

福建省永春双恒铝材有限公司,泉州 362619

多晶硅 定向凝固 不平衡散热 热应力 数值建模

厦门市自然科学基金项目厦门城市职业学院数字孪生智慧交通维修工程研究中心

3502Z202374052

2024

宇航材料工艺
航天材料及工艺研究所

宇航材料工艺

CSTPCD北大核心
影响因子:0.378
ISSN:1007-2330
年,卷(期):2024.54(4)