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高回弹有机硅改性聚酰亚胺泡沫材料的设计及性能

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设计合成了一系列新型高回弹有机硅改性聚酰亚胺泡沫材料(IBPIF-Si),对其泡孔结构、力学性能进行了测试,分析了其发泡原理,探究了材料的最高适用温度.结果表明,相比于纯IBPIF泡沫材料,IBPIF-Si泡沫材料具有低密度[(22.0±6.7)mg/cm3]、高孔隙率(97.93%)、优异的疏水性[水接触角为(128±2.72)°]、柔韧性(线性弹性区为0~14.77%).这一独特的改性方法拓宽了聚酰亚胺泡沫材料在航天领域中隔热、降噪、绝缘等方面的进一步应用.
Design and Properties of High Resilience Silicone Modified Polyimide Foam Materials
IIn this paper,a series of high resilience silicone-modified polyimide foams(IBPIF-Si)were prepared.The pore structure,mechanical properties,foaming principles and the highest operating temperature of IBPIF-Si were investigated.Compared to pure IBPIF,IBPIF-Si showed the low density[(22.0±6.7)mg/cm3)],high porosity(97.93%),excellent hydrophobic[the water contact angle was(128±2.72)°]and outstanding flexibility(with a linear elastic region was 0~14.77%).This unique modification method broadened the potential application of polyimide foam in the aerospace sector,including heat insulation,noise reduction,insulation and other aspects.

Organic siliconPolyimideFoamHigh resilienceHydrophobic

徐阳、王延东、徐昊成、袭锴

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南京大学高性能高分子材料与技术教育部重点实验室,南京 210023

有机硅 聚酰亚胺 泡沫 高回弹 疏水性

2024

宇航材料工艺
航天材料及工艺研究所

宇航材料工艺

CSTPCD北大核心
影响因子:0.378
ISSN:1007-2330
年,卷(期):2024.54(6)