盐湖研究2024,Vol.32Issue(2) :17-23.DOI:10.12119/j.yhyj.202402003

极端顶点法制备碳酸钙超疏水涂层

Preparation of Calcium Carbonate Superhydrophobic Coatings by Extreme Eertex Method

程远 吴鹏 刘鑫 乃学瑛 董亚萍
盐湖研究2024,Vol.32Issue(2) :17-23.DOI:10.12119/j.yhyj.202402003

极端顶点法制备碳酸钙超疏水涂层

Preparation of Calcium Carbonate Superhydrophobic Coatings by Extreme Eertex Method

程远 1吴鹏 1刘鑫 2乃学瑛 2董亚萍2
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作者信息

  • 1. 中国科学院青海盐湖研究所,中国科学院盐湖资源综合高效利用重点实验室,青海西宁 810008;青海盐湖资源综合利用技术研究开发中心,青海西宁 810008;中国科学院大学,北京 100049
  • 2. 中国科学院青海盐湖研究所,中国科学院盐湖资源综合高效利用重点实验室,青海西宁 810008;青海盐湖资源综合利用技术研究开发中心,青海西宁 810008
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摘要

目前,超疏水涂层存在着制备成本高、工艺复杂和环境污染等问题,阻碍了其工程化应用进程.文章以CaCO3晶须及其纳米粒子为填料,水性苯丙乳液为粘结剂,以及硬脂酸锌为疏水改性剂制备超疏水涂层.首先采用油酸对CaCO3晶须及其纳米粒子进行表面改性,然后基于极端顶点设计将改性后的CaCO3晶须、改性后的纳米CaCO3、苯丙乳液和硬脂酸锌为混合分量进行混料实验,以涂层接触角为响应变量建立回归模型,分析混合分量对接触角的影响.结果表明:采用不同形貌的CaCO3粉体复合苯丙乳液可制备出超疏水涂层,在纳米CaCO3与硬脂酸锌混合分量较高,CaCO3晶须混合分量较低以及苯丙乳液适中的区域,接触角可达153.5°.通过表面形貌分析,涂层的黏附性与其表面的孔洞有关,而较高的纳米CaCO3混合分量可降低涂层表面粗糙度,促进其超疏水性能.

Abstract

Large-scale engineering applications of superhydrophobic coatings have been restricted greatly owing to the high preparation cost,complex process and environmental pollution nowadays.In this work,CaCO3 whiskers and nanoparticles,water soluble styrene-acrylate emulsion,and zinc stearate were used to prepare superhydrophobic coatings,and CaCO3 whiskers and nanoparticles were used as fillers,water soluble styrene-acrylate emulsion was used as binder,and zinc stearate was used as binder hydrophobic modifier.Firstly,CaCO3 whisker and nanoparticles were surface modified.Then,superhydrophobic coatings can be fabricated based on extreme vertex design with modified CaCO3 whisker and nanoparticles,water soluble styrene-acrylic emulsion,and zinc stearate as the raw materials.And regression model was established to investigate the relationship between factor level and the contact angle.The results show that the superhy-drophobic coatings can be prepared by using CaCO3 powders with different morphologies combined with styrene-acrylic emulsion.In the region where the mixture fraction of nano-CaCO3 and zinc stearate are more and the mixture fraction of CaCO3 whisker are less,and the styrene-acrylic emulsion is moderate,the contact angle can reach up to 153.5°.Importantly,the adhesion of the coating was related to the pores on surface based on surface topography analysis.Moreover,results illustrated the surface roughness can be reduced and the superhydrophobicity can be promoted with increasing the content of CaCO3 nanoparticles.

关键词

碳酸钙晶须/苯丙乳液/超疏水/涂层/极端顶点法

Key words

Calcium carbonate whiskers/Styrene-acrylic emulsion/Superhydrophobicity/Coating/Extreme vertex method

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基金项目

青海省科技厅项目(2019-ZJ-7029)

出版年

2024
盐湖研究
中国科学院青海盐湖研究所

盐湖研究

CSTPCDCSCD
影响因子:0.319
ISSN:1008-858X
参考文献量25
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