盐湖研究2024,Vol.32Issue(6) :56-64.DOI:10.3724/j.yhyj.2024033

TBP和N523对H3BO3、HCl萃取性能对比研究

Comparative Study on Extraction Properties of TBP and N523 on H3BO3 and HCl

彭小五 时东 谢绍雷 张禹泽 姬连敏 李丽娟
盐湖研究2024,Vol.32Issue(6) :56-64.DOI:10.3724/j.yhyj.2024033

TBP和N523对H3BO3、HCl萃取性能对比研究

Comparative Study on Extraction Properties of TBP and N523 on H3BO3 and HCl

彭小五 1时东 1谢绍雷 1张禹泽 1姬连敏 1李丽娟1
扫码查看

作者信息

  • 1. 中国科学院青海盐湖研究所,盐湖资源绿色高值利用重点实验室,青海 西宁 810008;青海省盐湖资源综合利用工程技术中心,青海 西宁 810008
  • 折叠

摘要

文章以研究较多的从高镁锂比卤水中萃取提锂的中性磷酸酯类锂萃取剂"磷酸三丁酯"(TBP)和酰胺类锂萃取剂二-2-乙基己基乙酰胺(N523)为代表,系统考察了 TBP和N523对H3BO3和HCl的萃取性能.结果表明:TBP对H3BO3的萃取能力远强于N523,TBP与H3BO3形成的络合物结构为H3BO3·2TBP,MgCl2对TBP和N523萃取H3BO3均有明显的盐析效应;N523对HCl的萃取能力强于TBP,MgCl2和LiCl对TBP和N523萃取HCl均具有明显的盐析效应.

Abstract

In this paper,the extraction performance of neutral lithium phosphate extractant(TBP)and amide-based lithium extractant(N523)for H3BO3 and HCl was systematically investigated.The two extract-ants mentioned above were mainly applied to the study of lithium extraction from brines with high Mg/Li ra-tio.The results showed that the extraction ability of TBP for H3BO3was much stronger than that of N523,and the structure of the complex formed by TBP and H3BO3 was H3BO3-2TBP.MgCl2 has a significant salting-out effect on the extraction of boric acid by TBP and N523.The extraction ability of N523 for HCl was stronger than that of TBP,and MgCl2 and LiCl had a significant salting-out effect on HCl extraction by both TBP and N523.The results of the study can provide some theoretical guidance for the subsequent opti-mization of the process conditions of lithium extraction from boron-containing brines using these two types of lithium extractants.

关键词

TBP/N523/盐湖卤水/硼酸

Key words

TBP/N523/Salt lake brine/Boric acid

引用本文复制引用

出版年

2024
盐湖研究
中国科学院青海盐湖研究所

盐湖研究

CSTPCDCSCD
影响因子:0.319
ISSN:1008-858X
段落导航相关论文