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进口再生含铜金属物料的固体废物属性鉴别

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随着我国铜金属资源的缺口持续增大,对外依赖性不断增强,对进口再生含铜物料的准确高效鉴别显得尤为必要.本文建立了一种进口再生含铜金属物料的快速检验鉴别流程.以3起典型的进口再生含铜物料为案例,按照GB/T 38471-2019《再生铜原料》,对放射性污染物、表观特征、夹杂物含量、水分含量、金属总量、金属铜量、铜含量和金属回收率等指标进行检测并完成样品的来源分析,再依据GB 34330-2017《固体废物鉴别标准 通则》进行固体废物属性鉴别.鉴别结果表明,样品1为来源于铜加工或下游企业生产过程产生的余料,以及家用电器、机械设备、电气设备、换热器等经拆解、分选后所得,符合再生铜原料标准要求,为非固体废物;样品2为来源于不同规格/型号的电机、电器、变压器经拆解但未经剥离去除绝缘层的漆包线及其他含铜混合物料,属于丧失原有使用价值的物质,为固体废物;样品3为未经拆解、分选、加工和清洁的废五金和含有色金属的废碎料的混合物料,属于已丧失原有功能而无法继续使用的物质,为固体废物.通过制定快速检验鉴别流程,为进口含铜金属物料的固体废物鉴别和海关口岸监管提供技术支持.
Identification of solid waste properties of imported recycling copper-containing metal materials
As the gap of copper metal resources in China continues to increase,the foreign dependence is growing.Therefore,the accurate and efficient identification of imported recycling materials for copper is particularly necessary.In this paper,a rapid inspection and identification process for imported recycling copper-containing metal materials was established.Three typical cases of imported recycling copper-contai-ning metal materials were studied.In accordance with GB/T 38471-2019 Recycling Materials for Copper,the radioactive pollutants,apparent characteristics,foreign material content,moisture content,total metal content,metallic copper content,copper content,metal recycling rate and other indicators were tested to complete the source analysis of samples.Then the solid waste properties were identified in accordance with GB 34330-2017 Identification standards for solid waste General rules.The identification results showed that sample 1 was derived from the residual materials generated by copper processing or production process of downstream enterprises,as well as household appliances,mechanical equipment,electrical equipment and heat exchangers,after dismantling and sorting,which could meet the standard requirements for recycling materials for copper,and it belonged to non-solid waste.Sample 2 was enameled wire and other copper-con-taining mixed materials from different specifications/models of motors,electrical appliances and transform-ers dismantled without stripping to remove the insulating layer,which was a solid waste that had lost its o-riginal value of use.Sample 3 was a mixture of waste hardware and waste scrap containing non-ferrous met-als that had not been dismantled,sorted,processed and cleaned,and belonged to the waste metal that had lost its original function and could no longer be used,so they were solid wastes.Through the development of rapid identification process,this study provided technical support for the identification of solid wastes and customs port supervision of imported recycling for copper-containing materials.

recycling copper-containing metal materialsolid wasteidentification of property

胡小霞、吕晓华、萧达辉、张金龙、白桦

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乌鲁木齐海关技术中心,新疆乌鲁木齐 830000

广州海关技术中心,广东广州 510623

再生含铜金属物料 固体废物 属性鉴别

海关总署科研计划项目

2020HK260

2024

冶金分析
中国钢研科技集团有限公司(钢铁研究总院) 中国金属学会

冶金分析

CSTPCD北大核心
影响因子:1.124
ISSN:1000-7571
年,卷(期):2024.44(7)