首页|小型化远程激光诱导击穿光谱仪器研发及对合金钢中硅钼铬的分析

小型化远程激光诱导击穿光谱仪器研发及对合金钢中硅钼铬的分析

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为提升激光诱导击穿光谱(LIBS)技术在各种极端环境下的灵活分析能力,本研究实现了远程LIBS仪器的小型化设计.仪器采用模块化设计,以云台为底座,能够实现对远距离目标的灵活检测分析,采用8种合金钢标准样品为实验对象,在2 m条件下进行光谱采集,对标样中Si、Mo及Cr这3种元素进行定量分析.使用随机森林算法(RF)分别构建了上述3种元素的定量模型,模型决定系数分别为0.999 8、0.998 8、0.999 1.在对模型验证时,验证样品中Si、M o及Cr 3种元素预测含量的相对误差最小值分别为14.6%、12.9%、11.6%.所研发的小型化远程LIBS仪器具有良好的远程定量检测能力.
Development of miniaturized remote laser-induced breakdown spectroscopy instrument and its application in analysis of silicon,molybdenum and chromium in alloy steel
In order to improve the flexible analysis capability of laser-induced breakdown spectroscopy(LIBS)under various extreme environments,the miniaturization design of remote LIBS instrument was re-alized in this study.The instrument adopted modular design,and the tripod head was used as base sup-port.It was applicable for the flexible detection and analysis of remote targets.8 certified reference mate-rials of alloy steel were used as the experimental subject.The spectral acquisition was carried out under the condition of 2 m.3 elements in certified reference materials,including Si,Mo and Cr,were quantitatively analyzed.The quantitative models of 3 elements were established by random forest(RF)algorithm,and the coefficients of determination were 0.999 8,0.998 8 and 0.999 1,respectively.During the model vali-dation,the minimum relative errors of predicted contents of 3 elements(Si,Mo and Cr)in validation sam-ples were 14.6%,12.9%and 11.6%,respectively.The developed miniaturized remote laser-induced breakdown spectroscopy instrument showed good remote quantitative detection capability.

laser-induced breakdown spectroscopy(LIBS)miniaturizedremote analysisalloy steelsiliconmolybdenumchromiumrandom forest(RF)

宋骁冉、牛广辉、汤悦、许应铜、林庆宇、段忆翔

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桂林理工大学机械与控制工程学院,广西桂林 541004

宝武重工有限公司研发中心,上海 201900

四川大学机械工程学院,四川成都 610064

激光诱导击穿光谱(LIBS) 小型化 远程分析 合金钢 随机森林(RF)

2024

冶金分析
中国钢研科技集团有限公司(钢铁研究总院) 中国金属学会

冶金分析

CSTPCD北大核心
影响因子:1.124
ISSN:1000-7571
年,卷(期):2024.44(9)