首页|球形氧化铝与含氢硅油对有机硅导热灌封胶性能的影响

球形氧化铝与含氢硅油对有机硅导热灌封胶性能的影响

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采用端乙烯基硅油、球形氧化铝、铂催化剂、含氢硅油等制得加成型双组分有机硅导热灌封胶,研究了球形氧化铝复配质量比和粒径搭配、含氢硅油用量对灌封胶性能的影响.结果表明,采用平均粒径45 μm和5μm球形氧化铝复配作导热填料时,随着较小粒径(5 μm)球形氧化铝在导热填料中质量分数的增加,有机硅灌封胶的热导率先升后降.当5 μm球形氧化铝在导热填料中质量分数为40%时,有机硅灌封胶的热导率达到最大值1.63 W/(m·K);固定较大与较小粒径球形氧化铝质量比6∶4,随着较小粒径球形氧化铝粒径的减小,有机硅灌封胶的热导率和邵氏A硬度升高.随着较大粒径球形氧化铝粒的增大,有机硅灌封胶的热导率升高;随着交联剂含氢硅油用量的增加,有机硅灌封胶的可操作时间大幅缩短并趋于稳定,邵氏A硬度升高并趋于稳定.
Effects of Spherical Alumina and Hydrogen Silicone Oil on the Properties of Thermal Conductive Silicone Encapsulant
A two-component thermal conductive silicone encapsulant was prepared by end-vinyl silicone oil,spherical alumi-na,platinum catalyst and hydrogen silicone oil.The effects of the mass ratio and particle size of spherical alumina and the a-mount of hydrogen silicone oil on the properties of the silicone encapsulant were studied.The results show that when the spherical alumina with average particle size 45 μm and 5 μm is used as thermal conductive filler,silicone encapsulant increases the ther-mal conductivity first and then decreases with the increase of spherical alumina with smaller particle size(5 μm).When the mass fraction of 5 μm spherical alumina in the thermal conductive filler is 40%,the thermal conductivity of silicone encapsulant reaches the maximum of 1.63 W/(m·K).The mass ratio of large and small spherical alumina is 6∶4,the thermal conductivity and Shore A hardness of silicone encapsulant increases with the decrease of small size spherical alumina,and the thermal conduc-tivity of silicone encapsulant increases with the increase of large size spherical alumina.With the increase of hydrogen silicone oil,the silicone encapsulant shortens its operable time and tends to be stable,and Shore A hardness is increased and becomes stable.

silicone encapsulantthermal conductivityhardnessoperation time

吴生煜

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厦门捌斗新材料科技有限公司,福建厦门 361015

有机硅灌封胶 热导率 硬度 可操作时间

2024

有机硅材料
中国氟硅有机材料工业协会 中蓝晨光化工研究设计院有限公司 国家有机硅工程技术研究中心

有机硅材料

CSTPCD
影响因子:0.778
ISSN:1009-4369
年,卷(期):2024.38(3)
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