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硅基陶瓷前驱体快速裂解转化研究进展

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聚合物前驱体裂解转化法是制备陶瓷材料的重要方法之一,裂解是该工艺中不可或缺的步骤.传统的陶瓷前驱体热裂解方法存在升降温速率慢、工艺时间长、能耗高等问题.激光裂解、微波裂解、放电等离子烧结等新技术因具有升降温速率快、能量消耗低等优势,近年来受到材料领域研究者的关注.本文总结了快速裂解方法用于硅基前驱体转化陶瓷方面的研究进展,阐述了裂解新技术在高性能陶瓷材料制备中的技术优势.
Research Progress in Rapid Pyrolysis and Conversion of Silicon Based Ceramic Precursors
The polymer precursor derived ceramics route is one of the important ways for the preparation of ceramics,and py-rolysis is absolutely necessary in the process.The traditional thermal pyrolysis suffers from slow heating/cooling rate,long pro-cessing time,and high energy consumption.In recent years,new technologies,including laser pyrolysis,microwave treatment,and discharge plasma sintering,have attracted the attention in the researchers due to the advantages of fast heating/cooling rate and low energy consumption.This paper summarizes the research progress in rapid pyrolysis in PDCs.The advantages of the new technologies in the preparation of high-performance ceramics are also discussed.

ceramic precursorfast pyrolysislaser pyrolysismicrowave pyrolysis

陈楚童、陈艳杰、罗永明、张宗波、李永明、徐彩虹

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中国科学院化学研究所,中国科学院极端环境高分子材料重点实验室,北京 100190

中国科学院大学化学与化工学院,北京 100049

陶瓷前驱体 快速裂解 激光裂解 微波裂解

2024

有机硅材料
中国氟硅有机材料工业协会 中蓝晨光化工研究设计院有限公司 国家有机硅工程技术研究中心

有机硅材料

CSTPCD
影响因子:0.778
ISSN:1009-4369
年,卷(期):2024.38(3)
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