首页|空心玻璃微珠对双组分有机硅中空玻璃密封胶性能的影响

空心玻璃微珠对双组分有机硅中空玻璃密封胶性能的影响

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以α,ω-二羟基聚二甲基硅氧烷(107 硅橡胶)为基础聚合物,重质碳酸钙和纳米碳酸钙为补强填料制得双组分有机硅中空玻璃密封胶的A组分.以黑色浆、交联剂、偶联剂和催化剂制得B组分.将占A组分质量0%、0.5%、1.0%、1.5%和2.0%的107 硅橡胶,用等质量的空心玻璃微珠替代后制备密封胶,研究了空心玻璃微珠用量对A组分密度、黏度、挤出速率和成本的影响,以及对双组分密封胶表干时间、拉断时间、拉伸强度、断裂伸长率和耐老化性能的影响.结果表明,随着空心玻璃微珠用量从 0 增加到2.0%,A组分的密度和挤出速率、密封胶的断裂伸长率、单桶A组分成本降低,A组分黏度升高,混合后密封胶的表干时间和拉断时间缩短,密封胶的拉伸强度、热老化和水紫外老化性能均无明显变化.较佳的空心玻璃微珠用量为1.0%,此条件下制备双组分有机硅中空玻璃密封胶,A组分的密度为1.652 g/cm3、黏度为228 000 mPa·s、挤出速率为18 g/15 s,混合后密封胶的表干时间为47 min、拉断时间为75 min,固化后密封胶的拉伸强度为0.73 MPa、断裂伸长率为36.28%,单位体积A组分成本减少约0.5%.
Effect of Hollow Glass Beads on Properties of Two-Component Silicone Insulating Glass Sealant
The two-component silicone insulating glass sealant component A was prepared with α,ω-dihydroxy-polydimethi-cone(107 silicone rubber)as the base polymer,heavy calcium carbonate and nano-calcium carbonate as the reinforcing fillers,while component B was prepared with black paste,crosslinking agent,coupling agent and catalyst.The 107 silicone rubber,which accounted for 0%,0.5%,1.0%,1.5%and 2.0%of the mass of component A,was replaced by hollow glass beads with equal mass to prepare the sealant.The effects of the amount of hollow glass beads on the density,viscosity,extrusion rate and cost of component A were studied as well as its influence on the surface drying time,operation time,tensile strength,elongation at break and aging resistance of the two-component sealant.The results show that with the increase of the dosage of hollow glass beads from 0 to 2.0%,the density and extrusion rate of component A,the elongation at break of the sealant,the cost of compo-nent A per barrel decrease,the viscosity of component A increases,the surface drying time and breaking time of the sealant are shortened,and the tensile strength,thermal aging and water-ultraviolet aging properties of the sealant have no significant chan-ges.The optimal amount of glass micropheres is found to be 1.0wt%,under this condition,component A has the density of 1.652 g/cm3,the viscosity of 228 000 mPa·s,and the extrusion rate of 18 g/15 s.After mixing,the sealant has the surface dr-ying time of 47 min,and the pulling time of 75 min.The tensile strength of the cared sealant is 0.73 MPa,the elongation at break is 36.28%,and the cost component A of per unit volume is reduced by 0.5%.

two-componentinsulating glass sealanthollow glass beadslow density

琚龙云、蔡海涛、张翔

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湖北回天新材料股份有限公司,湖北襄阳 441000

双组分 中空玻璃密封胶 空心玻璃微珠 低密度

2024

有机硅材料
中国氟硅有机材料工业协会 中蓝晨光化工研究设计院有限公司 国家有机硅工程技术研究中心

有机硅材料

CSTPCD
影响因子:0.778
ISSN:1009-4369
年,卷(期):2024.38(5)